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Merck
CN

256048

Vanadium(V) oxychloride

99.995% trace metals basis

Synonym(s):

Trichlorooxovanadium oxide, Vanadium(V) oxytrichloride, Vanadyl trichloride

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About This Item

Linear Formula:
VOCl3
CAS Number:
7727-18-6
Molecular Weight:
173.30
UNSPSC Code:
12352302
PubChem Substance ID:
24855504
EC Number:
231-780-2
MDL number:
MFCD00011459

Key Documents

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InChI key

JBIQAPKSNFTACH-UHFFFAOYSA-K

InChI

1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3

SMILES string

Cl[V](Cl)(Cl)=O

vapor pressure

13.8 mmHg ( 20 °C)

assay

99.995% trace metals basis

form

liquid

reaction suitability

reagent type: catalyst
core: vanadium

bp

126-127 °C (lit.)

mp

−77 °C (lit.)

density

1.84 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

hcodes

H301,H314

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBB4206
01501BJ
14927PE
08920MW
13526AE

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Masayuki Kirihara et al.
Chemical & pharmaceutical bulletin, 52(5), 625-627 (2004-05-11)
Thiols were converted into disulfide by the aerobic oxidation catalyzed by trichlorooxyvanadium in the presence of molecular sieves 3A.
[Hygienic characteristics of the working conditions in the manufacture of vanadium hydroxychloride].
B G Feĭgin et al.
Gigiena truda i professional'nye zabolevaniia, (1)(1), 51-52 (1985-01-01)
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

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