256927
Ethylaluminum dichloride solution
1.0 M in hexanes
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About This Item
Linear Formula:
CH3CH2AlCl2
CAS Number:
Molecular Weight:
126.95
PubChem Substance ID:
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
4123357
MDL number:
vapor pressure
5 mmHg ( 60 °C)
form
liquid
concentration
1.0 M in hexanes
bp
68-70 °C
density
0.729 g/mL at 25 °C
SMILES string
CC[Al](Cl)Cl
InChI
1S/C2H5.Al.2ClH/c1-2;;;/h1H2,2H3;;2*1H/q;+2;;/p-2
InChI key
UAIZDWNSWGTKFZ-UHFFFAOYSA-L
Other Notes
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.
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signalword
Danger
target_organs
Nervous system, Respiratory system
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 2
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react. 1
Regulatory Information
监管及禁止进口产品
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Barry B Snider et al.
The Journal of organic chemistry, 68(16), 6451-6454 (2003-08-05)
EtAlCl(2)-induced cyclization of chiral gamma,delta-unsaturated ketones 11c and 17b takes place mainly from the expected face. The selectivity is modest for 11c (60:40) in which the large substituent is a primary alkyl group and the medium substituent is a methyl