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Merck
CN

257249

Tripropylaluminum

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About This Item

Linear Formula:
(CH3CH2CH2)3Al
CAS Number:
Molecular Weight:
156.24
UNSPSC Code:
12352103
PubChem Substance ID:
EC Number:
203-045-6
MDL number:
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InChI key

CNWZYDSEVLFSMS-UHFFFAOYSA-N

InChI

1S/3C3H7.Al/c3*1-3-2;/h3*1,3H2,2H3;

SMILES string

CCC[Al](CCC)CCC

bp

82-84 °C/2 mmHg (lit.)

mp

−107 °C (lit.)

density

0.823 g/mL at 25 °C (lit.)

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Application

Reactant involved in:
  • Studies of the kinetics and mechanism of Zr-catalyzed chain growth
  • Copper-catalyzed conjugate addition to nitrodienes and nitroenynes or oxabicyclohelptadienedicarboxylates
  • Copper-catalyzed stereoselective ring opening / desymmetrization of polycyclic meso-hydrazines or 1,4-dihydro-1,4-naphthalene epoxide
  • Synthesis of β-hydroxylactams via alkylative aldol cyclization with α,β-unsaturated carboxamides

Other Notes

Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.

pictograms

FlameCorrosion

signalword

Danger

Hazard Classifications

Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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