259004
3,6-Dibromocarbazole
97%
Synonym(s):
3,6-Dibromo-9-H-carbazole, 3,6-Dibromo-9H-carbazole
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About This Item
Empirical Formula (Hill Notation):
C12H7Br2N
CAS Number:
Molecular Weight:
325.00
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
powder
mp
204-206 °C (lit.)
SMILES string
Brc1ccc2[nH]c3ccc(Br)cc3c2c1
InChI
1S/C12H7Br2N/c13-7-1-3-11-9(5-7)10-6-8(14)2-4-12(10)15-11/h1-6,15H
InChI key
FIHILUSWISKVSR-UHFFFAOYSA-N
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General description
Lithiation of 3,6-dibromocarbazole with n-butyllithium has been studied.
Application
3,6-Dibromocarbazole has been used in the preparation of N-(2-hydroxyethyl)-3,6-dibromocarbazole.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A useful procedure for diiodination of carbazoles and subsequent efficient transformation to novel 3, 6-bis (triethoxysilyl) carbazoles giving mesoporous materials.
Maegawa Y, et al.
Tetrahedron Letters, 47(39), 6957-6960 (2006)
New NLO stilbene derivatives bearing phosphonate ester electron-withdrawing groups.
Belfield KD, et al.
Tetrahedron Letters, 38(35), 6131-6134 (1997)
Yan Wu et al.
Environmental science & technology, 52(8), 4536-4545 (2018-03-23)
Polyhalogenated carbazoles (PHCZs) were recently discovered in Great Lakes sediment and other aquatic systems. However, knowledge about their bioaccumulation and potential risks to fish and wildlife remains very limited. The present study investigated PHCZs in Great Lakes lake trout (
Li Fang et al.
Ecotoxicology and environmental safety, 184, 109609-109609 (2019-09-14)
Carbazole and halogenated carbazoles have been widely detected throughout the environment in soil, river deposits, and lake sediments. Human exposure to these compounds may occur through inhalation, drinking water, dietary intake and/or skin contact, and exposure levels in the body
Yanqiu Chen et al.
Environmental pollution (Barking, Essex : 1987), 232, 264-273 (2017-09-28)
Polyhalogenated carbazoles (PHCs) are a class of emerging organic contaminants that have received increasing concern due to their widespread distribution and dioxin-like toxicity. Although previous studies have suggested possible natural sources of PHCs in the environment, the formation pathways are
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