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Merck
CN

259004

3,6-Dibromocarbazole

97%

Synonym(s):

3,6-Dibromo-9-H-carbazole, 3,6-Dibromo-9H-carbazole

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About This Item

Empirical Formula (Hill Notation):
C12H7Br2N
CAS Number:
Molecular Weight:
325.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
powder
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InChI

1S/C12H7Br2N/c13-7-1-3-11-9(5-7)10-6-8(14)2-4-12(10)15-11/h1-6,15H

SMILES string

Brc1ccc2[nH]c3ccc(Br)cc3c2c1

InChI key

FIHILUSWISKVSR-UHFFFAOYSA-N

assay

97%

form

powder

mp

204-206 °C (lit.)

Quality Level

General description

Lithiation of 3,6-dibromocarbazole with n-butyllithium has been studied.

Application

3,6-Dibromocarbazole has been used in the preparation of N-(2-hydroxyethyl)-3,6-dibromocarbazole.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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New NLO stilbene derivatives bearing phosphonate ester electron-withdrawing groups.
Belfield KD, et al.
Tetrahedron Letters, 38(35), 6131-6134 (1997)
A useful procedure for diiodination of carbazoles and subsequent efficient transformation to novel 3, 6-bis (triethoxysilyl) carbazoles giving mesoporous materials.
Maegawa Y, et al.
Tetrahedron Letters, 47(39), 6957-6960 (2006)
Li Fang et al.
Ecotoxicology and environmental safety, 184, 109609-109609 (2019-09-14)
Carbazole and halogenated carbazoles have been widely detected throughout the environment in soil, river deposits, and lake sediments. Human exposure to these compounds may occur through inhalation, drinking water, dietary intake and/or skin contact, and exposure levels in the body
Yan Wu et al.
Environmental science & technology, 52(8), 4536-4545 (2018-03-23)
Polyhalogenated carbazoles (PHCZs) were recently discovered in Great Lakes sediment and other aquatic systems. However, knowledge about their bioaccumulation and potential risks to fish and wildlife remains very limited. The present study investigated PHCZs in Great Lakes lake trout (
Yanqiu Chen et al.
Environmental pollution (Barking, Essex : 1987), 232, 264-273 (2017-09-28)
Polyhalogenated carbazoles (PHCs) are a class of emerging organic contaminants that have received increasing concern due to their widespread distribution and dioxin-like toxicity. Although previous studies have suggested possible natural sources of PHCs in the environment, the formation pathways are

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