259039
Chloro(1,5-hexadiene)rhodium(I),dimer
98%
Synonym(s):
Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
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About This Item
Linear Formula:
[(H2C=CHCH2CH2CH=CH2)RhCl]2
CAS Number:
Molecular Weight:
434.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
assay
98%
InChI
1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2
SMILES string
Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C
InChI key
HXNWPVBAYNUADR-UHFFFAOYSA-L
reaction suitability
core: rhodium, reagent type: catalyst
mp
118-120 °C (lit.)
Application
Catalyst for:
- Hydrogenation
- Enantioselective hydrosilylation
Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Find documentation for the products that you have recently purchased in the Document Library.
Aldrichimica Acta, 18, 111-111 (1985)
Organometallics, 2, 1055-1055 (1983)
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