259063
(Methoxycarbonylmethyl)triphenylphosphonium bromide
98%
Synonym(s):
(Carbomethoxymethyl)triphenylphosphonium bromide, NSC 136109
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About This Item
Product Name
(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98%
InChI key
VCWBQLMDSMSVRL-UHFFFAOYSA-M
InChI
1S/C21H20O2P.BrH/c1-23-21(22)17-24(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1
SMILES string
[Br-].COC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
assay
98%
reaction suitability
reaction type: C-C Bond Formation
mp
165-170 °C (dec.) (lit.)
functional group
ester
phosphine
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Application
- GSK-3 inhibitors using theWittig reaction
- Substituted furanones for antifungal and cytostatic activities
- Photochromic dithienylethene derivatives
- Gem-diiodoalkanes containing allylic alcohols
- Highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization
Reactant for:
- Asymmetric hydrogenation of α,β-unsaturated ester-phosphonates
- Studies of thermal decomposition of phosphonium alkyl ester salts
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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