259616
4-Chlorobenzhydrazide
98%
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About This Item
Linear Formula:
ClC6H4CONHNH2
CAS Number:
Molecular Weight:
170.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-632-0
Beilstein/REAXYS Number:
511154
MDL number:
Assay:
98%
Form:
solid
InChI key
PKBGHORNUFQAAW-UHFFFAOYSA-N
InChI
1S/C7H7ClN2O/c8-6-3-1-5(2-4-6)7(11)10-9/h1-4H,9H2,(H,10,11)
SMILES string
NNC(=O)c1ccc(Cl)cc1
assay
98%
form
solid
Quality Level
functional group
amine, chloro, hydrazine
Related Categories
General description
Effect of acidic catalyst on the reaction of 4-chlorobenzhydrazide and β-naphthol in water has been investigated.
Application
4-Chlorobenzhydrazide has been used in preparation of:
- rod-shaped mesogenic hydrazide derivatives via Schotten-Baumann reaction with 4-n-alkoxybenzoyl chloride
- 4-methoxybenzaldehyde-4-chlorophenyl-1-carbonyl hydrazone
- 4-hydroxybenzaldehyde-4-chlorophenyl-1-carbonylhydrazone
- 2-nitrobenzaldehyde-4-chlorophenyl-1-carbonylhydrazone
- benzaldehyde-4-chlorophenyl-1-carbonylhydrazone
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Jagvir Singh et al.
Bioinorganic chemistry and applications, 2012, 104549-104549 (2012-11-06)
N-substituted pyridine hydrazide (pyridine-2-carbonyl chloride and 4-chloro-benzoic acid hydrazide) undergoes hydrazide formation of the iminic carbon nitrogen double bond through its reaction with cobalt(II), nickel(II), and copper(II) metal salts in ethanol which are reported and characterized based on elemental analyses
Minoo Dabiri et al.
Bioorganic & medicinal chemistry letters, 18(1), 436-438 (2007-12-07)
Alkyl- or aryl-14H-dibenzo[a,j]xanthene derivatives are synthesized efficiently by the reaction of beta-naphthol and aliphatic and aromatic aldehydes in the presence of KAl(SO4)2 x 12 H2O (alum) under aqueous condition at 100 degrees C. Different types of aromatic and aliphatic aldehydes
Synthesis of benzaldehyde substituted phenyl carbonyl hydrazones and their formylation using Vilsmeier-Haack reaction.
Rajput AP and Rajput AS.
International Journal of PharmTech Research, 1(4), 1605-1611 (2009)
Bent-shaped mesogenic oxadiazole and thiadiazole derivatives from rod-shaped mesogenic hydrazide containing polar chloro group.
Prajapati AK and Modi V.
Liq. Cryst., 37(4), 407-415 (2010)
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