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Merck
CN

261262

Scandium

powder, 99.9% trace rare earth metals basis

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About This Item

Empirical Formula (Hill Notation):
Sc
CAS Number:
Molecular Weight:
44.96
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141613
EC Number:
231-129-2
MDL number:
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Quality Level

assay

99.9% trace rare earth metals basis

form

powder

composition

Sc

reaction suitability

core: scandium

resistivity

50.5 μΩ-cm, 0°C

bp

2836 °C (lit.)

mp

1540 °C (lit.)

density

2.99 g/mL at 25 °C (lit.)

SMILES string

[Sc]

InChI

1S/Sc

InChI key

SIXSYDAISGFNSX-UHFFFAOYSA-N

Application

Employed in solid state synthesis of unusual clusters, Sc19Br28Z4, (Z=Mn, Fe, Ru or Os). These clusters are of interest for their structure and magnetic properties.


pictograms

Flame

signalword

Danger

hcodes

pcodes

Hazard Classifications

Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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Articles

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Andrea Olmos et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4894-4901 (2012-03-15)
This study demonstrates the first zeolite-catalyzed synthesis of piperidine derivatives, including peptidomimetics and indoloquinolizidine alkaloids. The approach developed utilizes a highly effective one-pot reaction cascade, through imine formation and imino-Diels-Alder reactions, promoted by scandium-loaded zeolites as a heterogeneous catalyst. The
Asymmetric synthesis of β-amino nitriles through a Sc(III)-catalyzed three-component Mannich reaction of silyl ketene imines.
Jiannan Zhao et al.
Angewandte Chemie (International ed. in English), 52(12), 3473-3477 (2013-02-14)
Jacob S Kanady et al.
Journal of the American Chemical Society, 135(3), 1073-1082 (2012-12-18)
The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable



Global Trade Item Number

SKUGTIN
261262-250MG04061838062581
261262-1G04061826597385