261483
N,N-Dimethylacetamide dimethyl acetal
90%
Synonym(s):
1,1-Dimethoxy-N,N-dimethylethylamine
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About This Item
Linear Formula:
CH3C(OCH3)2N(CH3)2
CAS Number:
Molecular Weight:
133.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1420865
Assay:
90%
Form:
liquid
Quality Level
assay
90%
form
liquid
refractive index
n20/D 1.411 (lit.)
bp
118 °C (lit.)
density
0.911 g/mL at 25 °C (lit.)
functional group
amine, ether
SMILES string
COC(C)(OC)N(C)C
InChI
1S/C6H15NO2/c1-6(8-4,9-5)7(2)3/h1-5H3
InChI key
FBZVZUSVGKOWHG-UHFFFAOYSA-N
General description
Claisen type reaction of N,N-dimethylacetamide dimethyl acetal using optically active trans-3-penten-2-ol as substrate has been investigated.
Application
N,N-Dimethylacetamide dimethyl acetal has been used as:
- one carbon inserting synthon in preparation of pyrimido[1,2-a][1,3,5]triazin-6-ones
- reagent for the synthesis of amides, diacylamines and heterocycles
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 2 - STOT SE 3
target_organs
Eyes,Central nervous system, Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
46.4 °F - closed cup
flash_point_c
8 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Nikhil Sachdeva et al.
Organic & biomolecular chemistry, 10(23), 4586-4596 (2012-05-15)
A novel thermal rearrangement, involving pyrimidine ring opening and subsequent ring closure leading to recyclization of the system, was identified in the reaction of (6-oxo-1,6-dihydropyrimidin-2-yl)guanidines 3 (where NR(1)R(2) = NH(2), NH alkyl, NH aralkyl, NHCH(2)Ph(R)) with triethyl orthoacetate, affording 4-substituted-2-methyl-6H-pyrimido[1,2-a][1,3,5]triazin-6-ones
Tetrahedron Letters, 33, 3449-3449 (1992)
Piotr Szustakiewicz et al.
Nanomaterials (Basel, Switzerland), 9(4) (2019-04-14)
In this study, we report a universal approach allowing the non-covalent deposition of gold nanoparticles on reduced graphene oxide surface in a controlled fashion. We used a modified Hummers method to obtain graphene oxide, which then underwent surficial functionalization with
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 261483-5G | 04061826107270 |
| 261483-25G | 04061837014512 |