262064
mono-Bromoborane methyl sulfide complex solution
1.0 M in methylene chloride
Synonym(s):
Bromo(dimethyl sulfide)borane, Bromo(dimethyl sulfide)dihydroboron
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About This Item
Linear Formula:
(CH3)2S·BH2Br
CAS Number:
Molecular Weight:
154.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352112
MDL number:
Form:
liquid
InChI
1S/C2H6S.BBrH2/c1-3-2;1-2/h1-2H3;1H2
SMILES string
BBr.CSC
InChI key
AQRNIOMHNXJPFD-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1.0 M in methylene chloride
density
1.347 g/mL at 25 °C
functional group
thioether
Quality Level
Related Categories
Application
Reactant for:
- Substitution reactions for synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds
- Hydroboration reactions
- Regio- and chemoselective brominative cleavage of terminal epoxides
supp_hazards
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
target_organs
Central nervous system
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
50.0 °F
flash_point_c
10 °C
Regulatory Information
危险化学品
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Andrey Solovyev et al.
Journal of the American Chemical Society, 132(42), 15072-15080 (2010-10-05)
Boryl halide, carboxylate and sulfonate complexes of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (dipp-Imd-BH(2)X, X = halide or sulfonate) have been prepared from the parent borane dipp-Imd-BH(3) by (1) substitution reactions with R-X (X = halide or sulfonate), (2) reactions with electrophiles (like I(2) or
Roy, C. D.; Brown, H. C.
Australian Journal of Chemistry, 60, 139-139 (2007)
Xaba, N.; Jaganyi, D.
Polyhedron, 28, 1145-1145 (2009)
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