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Merck
CN

262455

Bis(cyclopentadienyl)ruthenium(II)

97%

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About This Item

Empirical Formula (Hill Notation):
C10H10Ru
CAS Number:
1287-13-4
Molecular Weight:
231.26
NACRES:
NA.23
PubChem Substance ID:
24855742
UNSPSC Code:
12352103
EC Number:
215-065-2
MDL number:
MFCD00001442

Key Documents

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Product Name

Bis(cyclopentadienyl)ruthenium(II), 97%

InChI key

BKEJVRMLCVMJLG-UHFFFAOYSA-N

InChI

1S/2C5H5.Ru/c2*1-2-4-5-3-1;/h2*1-5H;

SMILES string

[Ru].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

mp

199-201 °C (lit.)

Quality Level

100

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX4488
MKCV3292
MKCQ7806
MKCP5799
MKCN2243

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M Schneider et al.
Zeitschrift fur Naturforschung. Section C, Biosciences, 37(1-2), 136-138 (1982-01-01)
In buffer solution (pH 7,4) ruthenocene and osmocene are far more stable than ferrocene. The metallocenes ruthenocene and osmocene are metabolized by microsomes of mouse liver in the presence of NADPH and O2. The Km-values are similar for both metallocenes
Adam J Salmon et al.
Chemical communications (Cambridge, England), 48(17), 2328-2330 (2012-01-20)
We have determined the protein X-ray crystal structures of four organometallic inhibitors in complex with their target enzyme carbonic anhydrase II. The barrel-shaped hydrophobic ferrocene and ruthenocene moieties have provided a structure-based avenue to better occupy the hydrophobic binding patch
M Wenzel et al.
International journal of radiation applications and instrumentation. Part A, Applied radiation and isotopes, 38(1), 67-69 (1987-01-01)
The radioactive decay of [103Ru]ruthenocene derivatives leads to 103mRh labelled rhodocinium derivatives, which can be separated by the extraction of a lipophilic solution of the ruthenocen derivate with water. The separation factor 103mRh/103Ru reaches values of 32:1 Rh3+ ions are
Malay Patra et al.
Chemical communications (Cambridge, England), 47(41), 11444-11446 (2011-09-22)
A convenient synthesis of azidomethyl-ruthenocene and its use in the covalent labelling of amino acids, peptides and a peptide nucleic acid (PNA) monomer derivative by Cu(I) catalyzed azide-alkyne coupling (Cu-AAC, "click chemistry") are described.
Cynthia T Sanderson et al.
Inorganic chemistry, 44(9), 3283-3289 (2005-04-26)
Electronic absorption and resonance Raman spectral studies of benzoylruthenocene (BRc) and 1,1'-dibenzoylruthenocene (DRc) indicate that the low-energy electronic excited states of these 4d(6) metallocenes possess metal-to-ligand charge transfer (MLCT) character. While this MLCT contribution should weaken the metal-ring bonding in
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