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Merck
CN

267317

Rhenium

foil, thickness 0.25 mm, 99.98% trace metals basis

Synonym(s):

Rhenium element

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About This Item

Empirical Formula (Hill Notation):
Re
CAS Number:
Molecular Weight:
186.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141737
MDL number:
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Product Name

Rhenium, foil, thickness 0.25 mm, 99.98% trace metals basis

InChI

1S/Re

SMILES string

[ReH]

InChI key

WUAPFZMCVAUBPE-UHFFFAOYSA-N

assay

99.98% trace metals basis

form

foil

description

19.3 μΩ-cm, 20°C

thickness

0.25 mm

bp

5596 °C (lit.)
5627 °C (lit.)

mp

3180 °C (lit.)

density

21.02 g/cm3 (lit.)

Quality Level

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Application

Rhenium can be used as a working electrode for electrochemical hydrogen evolution reactions.

It can be used as an additive to prepare a molybdenum-titanium-zirconium (TZM) alloy joint to improve its tensile strength.

It can also be used as a catalyst for various hydrodeoxygenation reactions.

General description

Rhenium is a very hard, corrosion, and wear-resistant rare metal with ahigh atomic number. It is widely used in the field of catalysis and the preparationof alloys for jet engines.

Preparation Note

3.3 g = 25 × 25 mm; 13.2 g = 50 × 50 mm

Storage Class

13 - Non Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Shalina C Bottorff et al.
Inorganic chemistry, 52(6), 2939-2950 (2013-03-06)
The viability of the Huisgen cycloaddition reaction for clickable radiopharmaceutical probes was explored with an alkyne-functionalized 2-[(pyridin-2-ylmethyl)amino]acetic acid (PMAA) ligand system, 3, and fac-[M(I)(OH2)3(CO)3](+) (M = Re, (99m)Tc). Two synthetic strategies, (1) click, then chelate and (2) chelate, then click
Yanfeng Jiang et al.
Journal of the American Chemical Society, 135(10), 4088-4102 (2013-02-07)
Diiodo Re(I) complexes [ReI2(NO)(PR3)2(L)] (3, L = H2O; 4 , L = H2; R = iPr a, Cy b) were prepared and found to exhibit in the presence of "hydrosilane/B(C6F5)3" co-catalytic systems excellent activities and longevities in the hydrogenation of
Jan Dietrich et al.
Inorganic chemistry, 52(3), 1248-1264 (2013-01-15)
New cationic metallo ligands L1-L3 based on bis(terpyridine) ruthenium(II) complexes decorated with differently substituted 2,2'-bipyridines attached via amide groups (5-NHCO-bpy, 4-CONH-bpy, 5-CONH-bpy) were prepared. Coordination of Re(I)Cl(CO)(3) fragments to the bpy unit gives the corresponding bimetallic Ru~Re complexes 1-3. Hydrogen
Cinzia Spagnul et al.
Journal of inorganic biochemistry, 122, 57-65 (2013-03-12)
The synthesis and characterization of two novel water soluble porphyrins with three meso pyridyl rings and one peripheral chelator - either a diethylenetriamine unit (4) or a bipyridyl fragment (8) - for binding to the {(99m)Tc(CO)3}(+) moiety is reported. In
Ties J Korstanje et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(39), 13224-13234 (2013-08-16)
Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the

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