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Merck
CN

267953

Iron

greener alternative

Greener Alternative

≥99.9% trace metals basis, powder, <10 μm

Synonym(s):

Fe

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About This Item

Linear Formula:
Fe
CAS Number:
Molecular Weight:
55.85
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101713
EC Number:
231-096-4
MDL number:
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Product Name

Iron, powder, <10 μm, ≥99.9% trace metals basis

Quality Segment

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product, Greener Alternative Product

resistivity

9.71 μΩ-cm

particle size

<10 μm

bp

2750 °C (lit.)

mp

1535 °C (lit.)

density

7.86 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Fe]

InChI

1S/Fe

InChI key

XEEYBQQBJWHFJM-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This is an enabling product and can be used to synthesize silicides for thermoelectric conversion, promoting energy efficiency. Click here for more information.

Application

Iron powder is commonly used as the catalyst for a wide variety of organic transformations. Applications include:
  • Reduction of nitroaromatic compounds to aromatic amines.
  • Iron-mediated polymerization of methyl methacrylate (MMA) in the presence of a reversible addition-fragmentation chain transfer (RAFT) agent, 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN).
  • Synthesis of pyrrolo[1,2-a]quinoxaline derivatives.
  • Conversion of ketoximes to the corresponding ketones by treatment with iron powder.
  • Iron-catalyzed cross-coupling reaction of imidazoles with vinyl bromides and vinyl chlorides.



pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Sol. 2 - Self-heat. 2

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

nwg

flash_point_f

69.8 °F

flash_point_c

21 °C

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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