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N-Benzoyl-N-phenylhydroxylamine

Name: <I>N</I>-Benzoyl-<I>N</I>-phenylhydroxylamine
Brand: ALDRICH

98%

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Synonym(s):

N-Hydroxy-N-phenylbenzamide, N-Phenylbenzohydroxamic acid

Linear Formula:

C₆H₅CON(OH)C₆H₅

CAS Number:

304-88-1

Molecular Weight:

213.23

Beilstein:

2212449

EC Number:

206-158-9

MDL number:

MFCD00002111

PubChem Substance ID:

24856609

NACRES:

NA.22

Quality Level

100

Assay

98%

form

powder

mp

118-120 °C (lit.)

storage temp.

2-8°C

SMILES string

ON(c1ccccc1)C(=O)c2ccccc2

InChI

1S/C13H11NO2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,16H

InChI key

YLYIXDZITBMCIW-UHFFFAOYSA-N

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General description

The mechanism of the reaction of N-benzoyl-N-phenylhydroxylamine with vanadium(IV) was studied.

Application

N-Benzoyl-N-phenylhydroxylamine was used as a complexing agent for studying the dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) behavior of vanadium (V). It was used as an extractant in the determination of beryllium in natural waters.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Reaction mechanism of N-benzoyl-N-phenylhydroxylamine with vanadium(IV) in the weakly acidic medium.

Z Nan

Talanta, 52(5), 785-789 (2008-10-31)

The N-benzoyl-N-phenylhydroxylamine(BPHA)-V(IV) system, if kept de-aerated, gives no color reaction. In an open vessel a color reaction does take place. This reaction was studied in solution by spectrophotometry, and the product prepared as solid by scanning thermal analysis, X-ray photoelectron

Determination of Trace Antimony (III) in Water Samples with Single Drop Microextraction Using BPHA-[C4mim][PF6] System Followed by Graphite Furnace Atomic Absorption Spectrometry.

Xiaoshan Huang et al.

International journal of analytical chemistry, 2018, 8045324-8045324 (2018-08-30)

A new sensitive method for antimony (III) determination by graphite furnace atomic absorption spectrometry (GFAAS) has been developed by using N-benzoyl-N-phenylhydroxylamine (BPHA) and 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) single drop microextraction. The single drop microextraction (SDMM) system is more competitive compared with

Flame atomic absorption spectrometric method for the determination of beryllium in natural waters after separation with N-benzoyl-N-phenylhydroxylamine.

L C Robles et al.

The Analyst, 116(7), 735-737 (1991-07-01)

A procedure for the determination of beryllium in natural waters is proposed. A solvent extraction step was performed in order to overcome interferences and isolate beryllium before it was atomized by direct nebulization of the organic phase in a dinitrogen

Determination of antimony(III) and total antimony by single-drop microextraction combined with electrothermal atomic absorption spectrometry.

Zhefeng Fan

Analytica chimica acta, 585(2), 300-304 (2007-03-28)

A simple and sensitive method for using electrothermal atomic absorption spectrometry (ET AAS) with Rh as permanent modifier determination of Sb(III) and total Sb after separation and preconcentration by N-benzoyl-N-phenylhydroxylamine (BPHA)-chloroform single drop has been developed. Parameters, such as pyrolysis

Determination of rhenium content in molybdenite by ICP-MS after separation of the major matrix by solvent extraction with N-benzoyl-N-phenylhydroxalamine.

Jie Li et al.

Talanta, 81(3), 954-958 (2010-03-20)

A simple and rapid analytical method for determining the concentration of rhenium in molybdenite for Re-Os dating was developed. The method used isotope dilution-inductively coupled plasma-mass spectrometry (ID-ICP-MS) after the removal of major matrix elements (e.g., Mo, Fe, and W)

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