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276669

1,1-Dimethylguanidine sulfate salt

Name: 1,1-Dimethylguanidine sulfate salt
Brand: ALDRICH

97%

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About This Item

Linear Formula:

[(CH₃)₂NC(NH₂)=NH]₂ · H₂SO₄

CAS Number:

598-65-2

Molecular Weight:

272.33

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24856711

EC Number:

209-946-0

Beilstein/REAXYS Number:

3916505

MDL number:

MFCD00013131

Assay:

97%

Form:

powder

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Properties

assay

97%

form

powder

mp

300 °C (dec.) (lit.)

functional group

amine

SMILES string

OS(O)(=O)=O.CN(C)C(N)=N.CN(C)C(N)=N

InChI

1S/2C3H9N3.H2O4S/c2*1-6(2)3(4)5;1-5(2,3)4/h2*1-2H3,(H3,4,5);(H2,1,2,3,4)

InChI key

QSCHFHVDZCPIKX-UHFFFAOYSA-N

Description

Application

1,1-Dimethylguanidine sulfate salt has been employed:

as peroxide activator for bleaching cellulosic textiles
in the synthesis of N²,N²-dimethyl-4-(1-methyl-1H-indol-3-yl)pyrimidine-2,5-diamine, substrate for the modified Pictet-Spengler reaction

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Engineering of indole-based tethered biheterocyclic alkaloid meridianin into β-carboline-derived tetracyclic polyheterocycles via amino functionalization/6-endo cationic π-cyclization.

Piyush Kumar Agarwal et al.

Beilstein journal of organic chemistry, 8, 1901-1908 (2012-12-05)

A mild, efficient and versatile method has been developed for the construction of a functionalized natural product, meridianin, and its post conversion to pyrimido-β-carboline by cationic π- cyclization. The strategy involves the introduction of an amino group at the C-5

Guanidine derivatives used as peroxide activators for bleaching cellulosic textiles.

Cai JY and Evans DJ.

Coloration Technology, 123(2), 115-118 (2007)

Structure-activity relationship between guanidine alkyl derivatives and norepinephrine release: site(s) and mechanism(s) of action.

J A Hirsch

The Journal of pharmacology and experimental therapeutics, 230(3), 710-717 (1984-09-01)

The effect of guanidine alkyl derivatives on the evoked release of [3H]norepinephrine [( 3H]NE) from spleen strips was examined. Guanidine, methyl guanidine and N,N-dimethyl guanidine all enhanced the field-stimulated release of [3H]NE 2- to 3-fold, whereas N,N'-dimethyl guanidine and propyl

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Global Trade Item Number

SKU	GTIN
276669-10G	04061826185551