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Merck
CN

276669

Sigma-Aldrich

1,1-Dimethylguanidine sulfate salt

97%

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About This Item

Linear Formula:
[(CH3)2NC(NH2)=NH]2 · H2SO4
CAS Number:
Molecular Weight:
272.33
Beilstein:
3916505
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay

97%

form

powder

mp

300 °C (dec.) (lit.)

functional group

amine

SMILES string

OS(O)(=O)=O.CN(C)C(N)=N.CN(C)C(N)=N

InChI

1S/2C3H9N3.H2O4S/c2*1-6(2)3(4)5;1-5(2,3)4/h2*1-2H3,(H3,4,5);(H2,1,2,3,4)

InChI key

QSCHFHVDZCPIKX-UHFFFAOYSA-N

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Application

1,1-Dimethylguanidine sulfate salt has been employed:
  • as peroxide activator for bleaching cellulosic textiles
  • in the synthesis of N2,N2-dimethyl-4-(1-methyl-1H-indol-3-yl)pyrimidine-2,5-diamine, substrate for the modified Pictet-Spengler reaction

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Guanidine derivatives used as peroxide activators for bleaching cellulosic textiles.
Cai JY and Evans DJ.
Coloration Technology, 123(2), 115-118 (2007)
Piyush Kumar Agarwal et al.
Beilstein journal of organic chemistry, 8, 1901-1908 (2012-12-05)
A mild, efficient and versatile method has been developed for the construction of a functionalized natural product, meridianin, and its post conversion to pyrimido-β-carboline by cationic π- cyclization. The strategy involves the introduction of an amino group at the C-5
W Zhang et al.
Acta physiologica Scandinavica, 159(1), 1-6 (1997-01-01)
1,1-dimethylguanidine (DMG) is an endogenous nitric oxide (NO) synthesis inhibitor. This study investigates the effects of exogenous DMG administration, in anaesthetized spontaneously hypertensive rats (SHR) and Wistar-Kyoto rats (WKY). Mean blood pressure (MBP), heart rate (HR) and renal sympathetic nerve
R Sopio et al.
Zeitschrift fur Lebensmittel-Untersuchung und -Forschung, 201(4), 381-386 (1995-10-01)
Deoxyosones are established key-intermediates in Maillard processes. Due to their dicarbonyl structure, they undergo condensation to form heterocyclic compounds with guanidine derivatives. In biological systems, guanidino functions are present in protein-bound arginine moieties as well as in creatine. The reactivity
E Benoit
Receptors & channels, 1(3), 181-191 (1993-01-01)
The effects of guanidine and dimethyl guanidine were studied on current- and voltage-clamped nodes of Ranvier, to determine the electrophysiological basis for the guanidine-induced increase in neurotransmitter release. When added to the external solution, guanidine produced positive shifts of K

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