276812
Phosphorus trichloride solution
2.0 M in methylene chloride
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About This Item
Linear Formula:
PCl3
CAS Number:
Molecular Weight:
137.33
PubChem Substance ID:
UNSPSC Code:
12352202
Beilstein/REAXYS Number:
969177
MDL number:
Form:
liquid
vapor pressure
23.32 psi ( 55 °C), 6.58 psi ( 20 °C)
form
liquid
concentration
2.0 M in methylene chloride
density
1.363 g/mL at 25 °C
SMILES string
ClP(Cl)Cl
InChI
1S/Cl3P/c1-4(2)3
InChI key
FAIAAWCVCHQXDN-UHFFFAOYSA-N
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3
target_organs
Central nervous system, Respiratory Tract
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Petri A Turhanen et al.
Organic & biomolecular chemistry, 1(18), 3223-3226 (2003-10-07)
Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from
Phosphorus trichloride-mediated and microwave-assisted synthesis of a small collection of amides bearing strong electron-withdrawing group substituted anilines.
Matteo Colombo et al.
Journal of combinatorial chemistry, 11(3), 335-337 (2009-03-31)
Núria Mont et al.
Molecular diversity, 13(1), 39-45 (2008-11-28)
A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, affords the corresponding 2-hydro-4-oxo-pyridopyrimidine 14, which is converted
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 276812-100ML | 04061838145628 |