277371
1-(Trimethylsilyl)pyrrolidine
97%
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About This Item
Empirical Formula (Hill Notation):
C7H17NSi
CAS Number:
Molecular Weight:
143.30
Beilstein:
1304636
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
liquid
refractive index
n20/D 1.433 (lit.)
bp
139-140 °C (lit.)
density
0.821 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)N1CCCC1
InChI
1S/C7H17NSi/c1-9(2,3)8-6-4-5-7-8/h4-7H2,1-3H3
InChI key
NQLVIKZJXFGUET-UHFFFAOYSA-N
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Application
1-(Trimethylsilyl)pyrrolidine (N-trimethylsilyl pyrrolidine) has been used in:
- ring opening reaction of L-serine β-lactone to yield corresponding 5-amino-L-alanine derivatives
- the preparation of iminium triflate salts
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
39.2 °F - closed cup
Flash Point(C)
4 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Exocyclic iminium salts as catalysts for alkene epoxidation by Oxone?.
Armstrong A, et al.
Tetrahedron, 55(8), 2341-2352 (1999)
Reaction of trimethylsilylamines with N-Cbz-l-serine-?-lactone: A convenient route to optically pure ?-amino-l-alanine derivatives.
Ratemi ES and Vederas JC.
Tetrahedron Letters, 35(41), 7605-7608 (1994)
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