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277681

3-Methyl-3-oxetanemethanol

Name: 3-Methyl-3-oxetanemethanol
Brand: ALDRICH

98%

Synonym(s):

3-Hydroxymethyl-3-methyl-oxetane

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About This Item

Empirical Formula (Hill Notation):

C₅H₁₀O₂

CAS Number:

3143-02-0

Molecular Weight:

102.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24856780

MDL number:

MFCD00010273

Beilstein/REAXYS Number:

102773

Assay:

98%

Form:

liquid

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Properties

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

80 °C/40 mmHg (lit.)

density

1.024 g/mL at 25 °C (lit.)

functional group

ether, hydroxyl

storage temp.

2-8°C

SMILES string

CC1(CO)COC1

InChI

1S/C5H10O2/c1-5(2-6)3-7-4-5/h6H,2-4H2,1H3

InChI key

NLQMSBJFLQPLIJ-UHFFFAOYSA-N

Description

Application

3-Methyl-3-oxetanemethanol has been used in the preparation of:

star-shaped copolymer consisting of a hyperbranched poly(3-methyl-3-oxetanemethanol) core and polytetrahydrofuran arms
pyridyl disulfide-functionalized cyclic carbonate monomer, required for the synthesis of of functional poly(ε-caprolactone) containing pendant pyridyl disulphide groups
δ-lactams

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

206.6 °F - closed cup

flash_point_c

97 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Functional poly (e-caprolactone) s via copolymerization of e-caprolactone and pyridyl disulfide-containing cyclic carbonate: controlled synthesis and facile access to reduction-sensitive biodegradable graft copolymer micelles.

Chen W, et al.

Macromolecules, 46(3), 699-707 (2013)

Synthesis of a Star-Shaped Copolymer with a Hyperbranched Poly (3-methyl-3-oxetanemethanol) Core and Tetrahydrofuran Arms by One-Pot Copolymerization.

Hou J and Yan D.

Macromolecular Rapid Communications, 23(8), 456-459 (2002)

Short stereoselective synthesis of alpha-substituted gamma-lactams.

Bhooma Raghavan et al.

The Journal of organic chemistry, 71(5), 2151-2154 (2006-02-25)

A concise, stereoselective synthesis of alpha-substituted gamma-lactams is reported. gamma-Lactam scaffolds 2 and 3, possessing an Evans' chiral auxiliary and two types of N substituents, were successfully alkylated with different electrophiles to give alpha-substituted gamma-lactams with reasonable diastereoselectivities. The use

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Global Trade Item Number

SKU	GTIN
277681-10G	04061838348401
277681-50G	04061837014604