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278688

9-Anthracenecarboxaldehyde

Name: 9-Anthracenecarboxaldehyde
Brand: ALDRICH

97%

Synonym(s):

9-Anthraldehyde

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About This Item

Empirical Formula (Hill Notation):

C₁₅H₁₀O

CAS Number:

642-31-9

Molecular Weight:

206.24

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24856824

EC Number:

211-383-0

Beilstein/REAXYS Number:

639167

MDL number:

MFCD00001254

Assay:

97%

Form:

solid

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Properties

assay

97%

form

solid

mp

103-105 °C (lit.)

functional group

aldehyde

SMILES string

[H]C(=O)c1c2ccccc2cc3ccccc13

InChI

1S/C15H10O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10H

InChI key

YMNKUHIVVMFOFO-UHFFFAOYSA-N

Description

General description

The Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied.

Application

9-Anthracenecarboxaldehyde has been used in the synthesis of:

new asymmetrical tridentate Schiff base ligands
2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol, novel Schiff base via condensation with 2-amino-p-cresol
functionalized ligand, 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione via Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Articles

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感应染料

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Knoevenagel condensation of the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopentene-1, 3-dione with 9-anthracenecarboxaldehyde: Synthesis of the second-generation ligand 2-(anthracen-9-ylidene)-4, 5-bis (diphenylphosphino)-4-cyclopentene-1, 3-dione.

Watson WH, et al.

Journal of Chemical Crystallography, 36(11), 715-722 (2006)

Zn(II), Ni(II), Cu(II) and Pb(II) complexes of tridentate asymmetrical Schiff base ligands: synthesis, characterization, properties and biological activity.

Mustafa Şahin et al.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 103, 400-408 (2013-01-01)

New asymmetrical tridentate Schiff base ligands were synthesized using 1,2-phenylenediamine, 4-methyl-1,2-phenylenediamine, 2-hydroxy-1-napthaldehyde, 9-anthracenecarboxaldehyde. Schiff base ligands and their metal complexes were synthesised and characterized by using FT-IR, (1)H NMR, (13)C NMR, UV-Vis, XRD, ESR, elemental analysis and fluorescence studies. The

Integrating reaction and analysis: investigation of higher-order reactions by cryogenic trapping.

Skrollan Stockinger et al.

Beilstein journal of organic chemistry, 9, 1837-1842 (2013-09-26)

A new approach for the investigation of a higher-order reaction by on-column reaction gas chromatography is presented. The reaction and the analytical separation are combined in a single experiment to investigate the Diels-Alder reaction of benzenediazonium-2-carboxylate as a benzyne precursor

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Global Trade Item Number

SKU	GTIN
278688-100G	04061826204757
278688-25G	04061826204771
278688-5G	04061826205006