279749
2-Methylaminomethyl-1,3-dioxolane
98%
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About This Item
Empirical Formula (Hill Notation):
C5H11NO2
CAS Number:
Molecular Weight:
117.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Product Name
2-Methylaminomethyl-1,3-dioxolane, 98%
InChI
1S/C5H11NO2/c1-6-4-5-7-2-3-8-5/h5-6H,2-4H2,1H3
SMILES string
CNCC1OCCO1
InChI key
ZCCPVTVGEQLONB-UHFFFAOYSA-N
assay
98%
refractive index
n20/D 1.4404 (lit.)
density
1.029 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
2-Methylaminomethyl-1,3-dioxolane was used in the synthesis of N-[methyl(2-hydroxy-3,5-dimethylphenyl)]-N-methyl-N-methyl-1,3-dioxolaneamine (mpoa-H).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Jakub Wojtaszak et al.
Dalton transactions (Cambridge, England : 2003), 43(6), 2424-2436 (2013-12-07)
The reaction of MgBu2, ZnEt2 or Ca(O(i)Pr)2 with 2 eq. of three-coordinating N-[methyl(2-hydroxy-3,5-dimethylphenyl)]-N-methyl-N-methyl-1,3-oxolaneamine (mpoa-H) or N-[methyl(2-hydroxy-3,5-di-tert-butylphenyl)]-N-methyl-N-methyl-1,3-oxolaneamine (tbpoa-H) gave neutral, monomeric [Mg(mpoa)2], [Zn(mpoa)2], [Zn(tbpoa)2], and [Ca(tbpoa)2] as white powders in 58-90% yields. The resulting aminophenolates were characterized in solution by NMR
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