281999
4-Bromobiphenyl
98%
Synonym(s):
(4-Bromophenyl)benzene, 1-Bromo-4-phenylbenzene, 4-Biphenyl bromide, 4′-Bromobiphenyl, p-Phenylphenyl bromide
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About This Item
Linear Formula:
C6H5C6H4Br
CAS Number:
Molecular Weight:
233.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-176-6
Beilstein/REAXYS Number:
1907453
MDL number:
Assay:
98%
Form:
solid
Quality Level
assay
98%
form
solid
bp
310 °C (lit.)
mp
82-86 °C (lit.)
functional group
bromo, phenyl
SMILES string
Brc1ccc(cc1)-c2ccccc2
InChI
1S/C12H9Br/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H
InChI key
PKJBWOWQJHHAHG-UHFFFAOYSA-N
General description
In vitro metabolism of 4-bromobiphenyl by cytochrome P-450-dependent monooxygenases in rat hepatic microsomes has been investigated. 4-Bromobiphenyl undergoes reduction to biphenyl in cationic micelles (cetyltrimethyl-ammonium bromide) by electrochemically generated anion radicals of 9-phenylanthracene.
Application
4-Bromobiphenyl was used in the synthesis of 4-biphenylthiolate.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Structure of 4-biphenylthiolate on Au nanoparticle surfaces studied by UV-Vis absorption spectroscopy, transmission electron microscopy and surface-enhanced Raman scattering.
Jang S, et al.
Surface and Interface Analysis : SIA, 36(1), 43-48 (2004)
Electrocatalytic reactions in organized assemblies: Part I. Reduction of 4-bromobiphenyl in cationic and non-ionic micelles.
Rusling JF, et al.
J. Electroanal. Chem. Interfac. Electrochem., 240(1), 201-216 (1988)
A D Davison et al.
Canadian journal of microbiology, 42(1), 66-71 (1996-01-01)
Sphingomonas paucimobilis BPSI-3 was previously isolated from a mixed microbial consortium growing on biphenyl as the sole source of carbon and energy. Transformation of 4-chlorobiphenyl (4CBP) was demonstrated by this strain, although little or no growth was observed. In minimal
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 281999-10G | 04061826225783 |
| 281999-50G | 04061826226018 |