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282146

(1R)-(−)-10-Camphorsulfonic acid

Name: (1<I>R</I>)-(−)-10-Camphorsulfonic acid
Brand: ALDRICH

98%

Synonym(s):

(−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₆O₄S

CAS Number:

35963-20-3

Molecular Weight:

232.30

UNSPSC Code:

12352106

NACRES:

NA.22

PubChem Substance ID:

24857020

EC Number:

252-817-9

Beilstein/REAXYS Number:

2809676

MDL number:

MFCD00064158

Assay:

98%

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Properties

Quality Level

100

assay

98%

optical activity

[α]20/D −21°, c = 2 in H₂O

mp

198 °C (dec.) (lit.)

functional group

ketone, sulfonic acid

SMILES string

[H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C

InChI

1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1

InChI key

MIOPJNTWMNEORI-XVKPBYJWSA-N

Description

General description

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Application

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films

Yin X, et al.

Biosensors And Bioelectronics, 21(11), 2184-2187 (2006)

Electrospun poly(methyl methacrylate)/polyaniline fibres as a support for laccase immobilisation and use in dye decolourisation.

Katarzyna Jankowska et al.

Environmental research, 184, 109332-109332 (2020-03-11)

Novel electrospun poly(methyl methacrylate)/polyaniline electrospun fibres were produced, characterised, modified, and used as a support for laccase immobilisation by two methods: adsorption and covalent binding. Effective deposition of laccase by both methods was confirmed by FTIR and CLSM results. Nevertheless

Synthesis and reactivity of chiral pentavalent bismuth derivatives

Finet PJ and Fedorov YA

Russian Chemical Bulletin, 53(7), 1488-1495 (2004)

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Global Trade Item Number

SKU	GTIN
282146-100G	04061826226254
282146-25G	04061826226261