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282146

(1R)-(−)-10-Camphorsulfonic acid

Name: (1<I>R</I>)-(−)-10-Camphorsulfonic acid
Brand: ALDRICH

98%

Synonym(s):

(−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₆O₄S

CAS Number:

35963-20-3

Molecular Weight:

232.30

UNSPSC Code:

12352106

NACRES:

NA.22

PubChem Substance ID:

24857020

EC Number:

252-817-9

Beilstein/REAXYS Number:

2809676

MDL number:

MFCD00064158

Assay:

98%

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Properties

Quality Segment

100

assay

98%

optical activity

[α]20/D −21°, c = 2 in H₂O

mp

198 °C (dec.) (lit.)

functional group

ketone, sulfonic acid

SMILES string

[H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C

InChI

1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1

InChI key

MIOPJNTWMNEORI-XVKPBYJWSA-N

Description

General description

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Application

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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