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282537

1,8-Dimethylnaphthalene

Name: 1,8-Dimethylnaphthalene
Brand: ALDRICH

95%

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About This Item

Linear Formula:

C₁₀H₆(CH₃)₂

CAS Number:

569-41-5

Molecular Weight:

156.22

EC Number:

209-314-4

UNSPSC Code:

12352100

PubChem Substance ID:

24857052

Beilstein/REAXYS Number:

2039841

MDL number:

MFCD00004040

Assay:

95%

Form:

solid

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Properties

assay

95%

form

solid

bp

270 °C (lit.)

mp

59-61 °C (lit.)

SMILES string

Cc1cccc2cccc(C)c12

InChI

1S/C12H12/c1-9-5-3-7-11-8-4-6-10(2)12(9)11/h3-8H,1-2H3

InChI key

XAABPYINPXYOLM-UHFFFAOYSA-N

Description

General description

Mechanism of NO(2)(+) nitration of 1,8-dimethylnaphthalene has beeen investigated. Photolysis of the 1,8-dimethylnaphthalene/tetranitromethane charge-transfer complex affords the triad of 1,8-dimethylnaphthalene radical cation, nitrogen dioxide and trinitromethanide ion.

Application

1,8-Dimethylnaphthalene has been used in the preparation of 1,4-endoperoxides via dyesensitized photo-oxygenation reaction.

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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