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283444

3,5-Diiodosalicylaldehyde

Name: 3,5-Diiodosalicylaldehyde
Brand: ALDRICH

97%

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About This Item

Linear Formula:

I₂C₆H₂-2-(OH)CHO

CAS Number:

2631-77-8

Molecular Weight:

373.91

NACRES:

NA.22

PubChem Substance ID:

24857104

UNSPSC Code:

12352100

EC Number:

220-117-2

MDL number:

MFCD00003321

Assay:

97%

Form:

solid

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Properties

Quality Level

200

assay

97%

form

solid

mp

109-110 °C (lit.)

functional group

aldehyde, iodo

SMILES string

Oc1c(I)cc(I)cc1C=O

InChI

1S/C7H4I2O2/c8-5-1-4(3-10)7(11)6(9)2-5/h1-3,11H

InChI key

MYWSBJKVOUZCIA-UHFFFAOYSA-N

Description

Application

3,5-Diiodosalicylaldehyde has been used in the synthesis of:

new Schiff bases, (2,4-diiodo-6-[(2-morpholin-4-yl-ethylimino)-methyl]-phenol and 2,4-diiodo-6-[(3-morpholin-4-yl-propylimino)-methyl]-phenol)
new tridentate ligand, [(2-hydroxy-3,5-diiodo-benzylidene)-amino]-acetic acid (HDBA)
3-bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis and antibacterial activities of metal (II) complexes with Schiff bases derived from 3, 5-diiodosalicylaldehyde.

Xu S-P, et al.

Journal of Coordination Chemistry, 62(12), 2048-2057 (2009)

3-Bromo-N'-(2-hydr-oxy-3,5-diiodo-benzyl-idene)benzohydrazide monohydrate.

Jing-Heng Ning et al.

Acta crystallographica. Section E, Structure reports online, 65(Pt 4), o905-o906 (2009-01-01)

Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo-benzohydrazide with 3,5-diiodo-salicylaldehyde. The Schiff base mol-ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is

Synthesis and antibacterial activities of copper (II) with [(2-hydroxy-3, 5-diiodo-benzylidene)-amino]-acetic acid.