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283606

Palladium(II) chloride solution

5 wt. % in 10 wt. % HCl, liquid

Synonym(s):

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

Linear Formula:
PdCl2
CAS Number:
7647-10-1
Molecular Weight:
177.33
UNSPSC Code:
12161600
PubChem Substance ID:
24857119
NACRES:
NA.22
MDL number:
MFCD00003558
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Product Name

Palladium(II) chloride solution, 5 wt. % in 10 wt. % HCl

form

liquid

Quality Level

100

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

concentration

5 wt. % in 10 wt. % HCl

density

1.06 g/mL at 25 °C

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

General description

Palladium(II) chloride is a representative salt of Pd(II) that is used as a precursor to prepare palladium catalysts for various reactions, such as Heck coupling, Suzuki coupling, Sonagashira coupling, and Buchwald-Hartwig coupling. It is also used as an oxidizing agent.

Application

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Storage Class

12 - Non Combustible Liquids

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB3803
MKCZ3569
MKCX1320
MKCT5872
MKCR2109

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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Maozhong Miao et al.
Organic letters, 14(11), 2718-2721 (2012-05-16)
A novel PdCl(2)-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused cyclobutene intermediates, is reported. An interesting route to 2(3H)-furanones with a spiro-cyclopropane unit from the obtained 2-alkylidenecyclobutanones via a ring-contraction rearrangement reaction
Yves Canac et al.
Inorganic chemistry, 50(21), 10810-10819 (2011-10-11)
The influence of the formal electrostatic interaction on the cis/trans coordination mode at a PdCl(2) center is investigated in a family of isostructural flexible diphosphine ligands Ph(2)P-X-C(6)H(4)-Y-PPh(2), where X and Y stand for neutral or cationic N,C-imidazolylene linkers. While the
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Global Trade Item Number

SKUGTIN
283606-50ML04061826245927