283630
Vinylferrocene
97%, solid
Synonym(s):
Ethenylferrocene
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About This Item
Empirical Formula (Hill Notation):
C12H12Fe
CAS Number:
Molecular Weight:
212.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-041-1
MDL number:
Product Name
Vinylferrocene, 97%
InChI key
LCPVTGDQYVLJHU-UHFFFAOYSA-N
InChI
1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H;
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C=C[C]2[CH][CH][CH][CH]2
assay
97%
form
solid
reaction suitability
core: iron
reagent type: catalyst
bp
80-85 °C/0.2 mmHg (lit.)
mp
51-53 °C (lit.)
Quality Level
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Application
Synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.
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Joachim Loup et al.
Angewandte Chemie (International ed. in English), 56(45), 14197-14201 (2017-09-19)
Highly enantioselective iron-catalyzed C-H alkylations by inner-sphere C-H activation were accomplished with ample scope. High levels of enantiocontrol proved viable through a novel ligand design that exploits a remote meta-substitution on N-heterocyclic carbenes within a facile ligand-to-ligand H-transfer C-H cleavage.
Ryoji Kurita et al.
Biosensors & bioelectronics, 20(3), 518-523 (2004-10-21)
This paper proposes a very simple procedure for preparing a biocompatible sensor based on a protein (bovine serum albumin, BSA), enzyme and vinylferrocene (VF) composite membrane modified electrode. The membrane was prepared simply by first casting vinylferrocene and then coating
Ceren Kaçar et al.
Analytical and bioanalytical chemistry, 409(11), 2873-2883 (2017-02-12)
Highly sensitive L-lysine enzyme electrodes were constructed by using poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine (PVF/MWCNTs-GEL) and poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine-graphene (PVF/MWCNTs-GEL/GR) composites as sensing interfaces and their performances were evaluated. Lysine oxidase (LO) was immobilized onto the composite modified glassy carbon electrodes (GCE)
Atsunori Hiratsuka et al.
Biosensors & bioelectronics, 21(6), 957-964 (2005-11-01)
We propose a new strategy for constructing a mediator-type biosensor as a Bio-MicroElectroMechanical Systems (BioMEMS) application. A vinylferrocene plasma-polymerized film (PPF) was deposited directly onto the surface of an electrode under dry conditions. The resulting redox film was extremely thin
Kay L Robinson et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 24(3), 339-343 (2008-03-12)
Poly(vinylferrocene) (pVFc) homopolymer was synthesized by free radical polymerization, along with a series of pVFc-based copolymers containing either styrene, vinylanthracene or methylmethacrylate. This report details the electrochemical experiments conducted to examine the stability of the various pVFc based polymers, which
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