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About This Item
Linear Formula:
(CH3)3CSi(CH3)2OH
CAS Number:
Molecular Weight:
132.28
Beilstein:
1732777
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
99%
form
liquid
refractive index
n20/D 1.424 (lit.)
bp
139 °C/739 mmHg (lit.)
density
0.84 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)[Si](C)(C)O
InChI
1S/C6H16OSi/c1-6(2,3)8(4,5)7/h7H,1-5H3
InChI key
FGWRMMTYIZKYMA-UHFFFAOYSA-N
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Application
tert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:
- For the preparation of α-chiral ether derivatives by catalytic asymmetric allylic substitution.
- As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.
- In the synthesis of enol silyl ethers.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
113.0 °F - closed cup
Flash Point(C)
45 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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