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290068

Zinc trifluoromethanesulfonate

Name: Zinc trifluoromethanesulfonate
Brand: ALDRICH

98%

Synonym(s):

Bis(trifluoromethanesulfonato)zinc, Zinc trifluoromethylsulfonate, Zn(OTf)2, Trifluoromethanesulfonic acid zinc salt, Zinc triflate, Zn(OTf)₂

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About This Item

Linear Formula:

(CF₃SO₃)₂Zn

CAS Number:

54010-75-2

Molecular Weight:

363.53

UNSPSC Code:

12161600

NACRES:

NA.22

PubChem Substance ID:

24857423

EC Number:

258-922-6

Beilstein/REAXYS Number:

4028195

MDL number:

MFCD00013229

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Properties

Quality Level

200

assay

98%

reaction suitability

core: zinc, reagent type: catalyst

greener alternative product characteristics

Catalysis
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Greener Alternative Product

mp

≥300 °C (lit.)

greener alternative category

, Aligned

SMILES string

[Zn++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

CITILBVTAYEWKR-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Zinc trifluoromethanesulfonate acts as a lewis acid in nucleophilic addition and as a catalyst in aldol reactions.

Application

Initiating a high-temperature zinc ion battery through a triazolium-based ionic liquid: This study explores the use of zinc trifluoromethanesulfonic acid in ionic liquid for high-temperature zinc ion batteries, demonstrating significant improvements in conductivity and stability. (Li et al., 2022).
Enhancing the solubility of 6-mercaptopurine by formation of ionic cocrystal with zinc trifluoromethanesulfonate: The research focuses on improving the solubility of 6-mercaptopurine by forming ionic cocrystals with zinc trifluoromethanesulfonate, resulting in single-crystal-to-single-crystal transformation. (Yao et al., 2014).
Spontaneous desaturation of the solvation sheath for high-performance anti-freezing zinc-ion gel-electrolyte: This paper discusses the development of a high-performance anti-freezing zinc-ion gel-electrolyte using zinc trifluoromethanesulfonate, which shows excellent performance even at low temperatures. (Li et al., 2023).

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Novel heterogeneous zinc triflate catalysts for the rearrangement of ?-pinene oxide.

Wilson K, et al.

Catalysis Letters, 61(1-2), 51-55 (1999)

Regioselective synthesis of 3-alkylindoles mediated by zinc triflate.

Zhu X and Ganesan A

The Journal of Organic Chemistry, 67(8), 2705-2708 (2002)

Magnesium and zinc-catalyzed thioketalization

Corey EJ and Shimoji K

Tetrahedron Letters, 24, 169-169 (1983)

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Global Trade Item Number

SKU	GTIN
290068-200G	04065270986603
290068-10G	04061826285206
290068-50G	04061826285220