292621
Ethyl 2-chloro-2-(hydroxyimino)acetate
97%
Synonym(s):
1-Ethyl oxalyl chloride 2-oxime
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About This Item
Linear Formula:
HON=C(Cl)CO2C2H5
CAS Number:
Molecular Weight:
151.55
Beilstein:
606193
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
97%
form
solid
mp
70-76 °C (lit.)
functional group
amine
chloro
ester
oxime
storage temp.
2-8°C
SMILES string
CCOC(=O)\C(Cl)=N\O
InChI
1S/C4H6ClNO3/c1-2-9-4(7)3(5)6-8/h8H,2H2,1H3/b6-3-
InChI key
UXOLDCOJRAMLTQ-UTCJRWHESA-N
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Application
Ethyl 2-chloro-2-(hydroxyimino)acetate has been used:
- in the preparation of (+)-and (−)-Δ2-isoxazolines
- in the synthesis of CIP-AS (−), a chiral amino acid structurally related to glutamic acid, potential agonist at the ionotropic (±±)-2-amino-3-(3-hydroxy-5-methylisoxazol-4-yl)propionic acid (AMPA)-kainate receptors
- to generate ethoxycarbonylformonitrile oxide, in situ by treatment with sodium bicarbonate
- to prepare N-azirdinyloximes which on treatment with scandium triflate (418218) provide dihydro-oxadiazines
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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