292710
Phenyl β-D-glucopyranoside
≥95.0%
Synonym(s):
Phenyl beta-D-glucoside
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About This Item
Empirical Formula (Hill Notation):
C12H16O6
CAS Number:
Molecular Weight:
256.25
UNSPSC Code:
12352201
NACRES:
NA.22
PubChem Substance ID:
EC Number:
215-978-6
Beilstein/REAXYS Number:
87517
MDL number:
Product Name
Phenyl β-D-glucopyranoside, ≥95.0%
InChI key
NEZJDVYDSZTRFS-RMPHRYRLSA-N
InChI
1S/C12H16O6/c13-6-8-9(14)10(15)11(16)12(18-8)17-7-4-2-1-3-5-7/h1-5,8-16H,6H2/t8-,9-,10+,11-,12-/m1/s1
SMILES string
OC[C@H]1O[C@@H](Oc2ccccc2)[C@H](O)[C@@H](O)[C@@H]1O
assay
≥95.0%
form
powder
optical activity
[α]25/D −70°, c = 1 in H2O
mp
176-178 °C (lit.)
Quality Level
Application
Phenyl β-D-glucopyranoside can be used:
- As a starting material for the synthesis of various derivatives of β-D-glucopyranosides with potential application as anti-HIV agents.
- As a model for glycosides in the gas phase for their spectroscopic investigation.
- As an internal standard in GC and GC-MS quantitative analyses.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
涉药品监管产品
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Chunyan Bao et al.
Carbohydrate research, 339(7), 1311-1316 (2004-04-29)
A new hydrogel based on a substituted phenyl glucoside with a Schiff base in the aglycon was synthesized, and the self-assembling characteristics was studied. FTIR spectra, UV-vis absorption spectra and X-ray diffraction (XRD) revealed that pi-pi interactions between the Schiff
Ying Na et al.
Bioorganic chemistry, 39(3), 111-113 (2011-03-26)
The spontaneous hydrolysis of glycosylamines, where the aglycone is either a primary amine or ammonia, is over a hundred million-times faster than that of O- or S-glycosides. The reason for this (as pointed out by Capon and Connett in 1965)
V T Edwards et al.
Xenobiotica; the fate of foreign compounds in biological systems, 16(9), 801-807 (1986-09-01)
The metabolic fates of 14C-phenol and its model plant conjugates 14C-phenyl glucoside and 14C-phenyl 6-O-malonyl-glucoside have been compared following equimolar oral dosing to rats (1.2 mg phenol/kg). Rapid excretion of radioactivity in the urine (at least 80% within 24 h)
Udayanath Aich et al.
Carbohydrate research, 341(1), 19-28 (2005-11-26)
Reported is an attractive and environmentally friendly method for the synthesis of the title compounds in moderate yield using inexpensive 1,2,3,4,6-penta-O-acetyl-beta-D-gluco- and galactopyranoses as sugar donors, five different phenols as acceptors and H-beta zeolite as the catalyst. The yield (23-28%)
Emission of 2-phenylethanol from its ?-D-glucopyranoside and the biogenesis of these compounds from [2H8] L-phenylalanine in rose flowers.
Hayashi S, et al.
Tetrahedron, 60(33), 7005-7013 (2004)
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