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Merck
CN

292966

Sigma-Aldrich

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

95%, solid

Synonym(s):

BNDHP

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About This Item

Empirical Formula (Hill Notation):
C20H13O4P
CAS Number:
35193-63-6
Molecular Weight:
348.29
EC Number:
252-425-8
MDL number:
MFCD00010045
UNSPSC Code:
12352005
PubChem Substance ID:
24857622
NACRES:
NA.22

Key Documents

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Product Name

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, 95%

Quality Level

100

Assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

SMILES string

OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45

InChI

1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)

InChI key

JEHUZVBIUCAMRZ-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
02317DJ
00718JM

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Dorothee Wistuba et al.
Electrophoresis, 27(21), 4359-4363 (2006-10-06)
Native delta-CD has been employed as chiral selector in CE and MEKC. To investigate the potential of the enantiodiscriminating properties of delta-CD, negatively charged 5-dimethylamino-1-naphthalene-sulfonyl (dansyl)-, 2,4-dinitrophenyl (DNP)- and FMOC-derivatives of several amino acids, 1,1'-binaphthyl-2,2'-diylhydrogenphosphate, flavanones and three positively charged
Tom M H Choy et al.
Electrophoresis, 24(18), 3116-3123 (2003-10-01)
The feasibility of employing the "acetonitrile stacking" method in micellar electrokinetic chromatography (MEKC) for the on-line preconcentration and separation of enantiomers is demonstrated for the first time. The effects of various experimental parameters on the stacking and separation of three
B Chankvetadze et al.
Journal of chromatography. A, 773(1-2), 331-338 (1997-06-27)
Selected water-soluble, native polysaccharides--such as amylose, laminaran, pullulan--and derivatized polysaccharides--methyl cellulose, hydroxypropyl cellulose, and carboxymethyl amylose sodium salt (CM-Am)--were investigated as chiral selectors in capillary electrophoresis. Effects of degree of polymerization and concentration of amylose on the separation of enantiomers
Simon M Mwongela et al.
Journal of separation science, 30(9), 1334-1342 (2007-07-12)
In this study, we report the effects of adding ionic liquids (ILs), as compared to adding conventional molecular organic solvents (MOSs), to aqueous buffer solutions containing molecular micelles in the separation of chiral analyte mixtures in micellar EKC (MEKC). The
Fluorescence anisotropy as a measure of chiral recognition.
M E McCarroll et al.
Journal of the American Chemical Society, 123(13), 3173-3174 (2001-07-18)
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