293113
Sulfur monochloride solution
1.0 M in methylene chloride
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About This Item
Empirical Formula (Hill Notation):
Cl2S2
CAS Number:
Molecular Weight:
135.04
UNSPSC Code:
12352302
PubChem Substance ID:
MDL number:
Form:
liquid
InChI
1S/Cl2S2/c1-3-4-2
SMILES string
ClSSCl
InChI key
PXJJSXABGXMUSU-UHFFFAOYSA-N
vapor density
4.7 (vs air)
vapor pressure
25.05 psi ( 55 °C), 7.31 psi ( 20 °C)
form
liquid
autoignition temp.
451 °F
concentration
1.0 M in methylene chloride
Packaging
Packaged under nitrogen in Sure/Seal™ bottles
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
监管及禁止进口产品
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M J Davies et al.
Free radical research, 33(6), 719-729 (2001-03-10)
Activated phagocytic cells generate hypochlorite (HOCl) via release of hydrogen peroxide and the enzyme myeloperoxidase. HOCl plays an important role in bacterial cell killing, but excessive or misplaced production of HOCI is also known to cause tissue damage. Studies have
[Eye burn caused by sulfur monochloride].
J Peyresblanques et al.
Bulletin des societes d'ophtalmologie de France, 87(3), 429-430 (1987-03-01)
Daniel K W Mok et al.
The Journal of chemical physics, 125(10), 104303-104303 (2006-09-27)
Geometry optimization calculations were carried out on the (approximate)X (1)A(1) state of SCl(2) and the (approximate)X(2)B(1), (approximate)A(2)B(2), (approximate)B(2)A(1), (approximate)C(2)A(1), (approximate)D(2)A(2), and (approximate)E (2)B(2) states of SCl(2) (+) at the restricted-spin coupled-cluster single-double plus perturbative triple excitation [RCCSD(T)] level with basis
F Machetti et al.
Advances in experimental medicine and biology, 483, 399-401 (2002-01-15)
(+/-)trans 2-Aminocyclohexanesulfonic acid and (+/-)trans 2-aminocyclopentanesulfonic acid were prepared from cyclohexene and cyclopentene respectively by sulfur monochloride addition, followed by oxidation to 2-chlorosulfonic acid and substitution of chlorine.
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