Key Documents

View All Documentation

294071

Methoxymethyl phenyl sulfide

Name: Methoxymethyl phenyl sulfide
Brand: ALDRICH

97%

Synonym(s):

[(Methoxymethyl)thio]benzene

Select a Size

Change View

About This Item

Linear Formula:

C₆H₅SCH₂OCH₃

CAS Number:

13865-50-4

Molecular Weight:

154.23

UNSPSC Code:

12352100

PubChem Substance ID:

24857701

MDL number:

MFCD00008496

Assay:

97%

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

assay

97%

refractive index

n20/D 1.5632 (lit.)

bp

113-114 °C/18 mmHg (lit.)

density

1.047 g/mL at 25 °C (lit.)

functional group

ether, thioether

SMILES string

COCSc1ccccc1

InChI

1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI key

QPXQVNXSQCRWEV-UHFFFAOYSA-N

Description

General description

Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.

Application

Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

203.0 °F - closed cup

flash_point_c

95 °C - closed cup

ppe

Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

MKBQ8863V

16013KA

04309DY

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.

Maricich TJ and Harrington CK.

Journal of the American Chemical Society, 94(14), 5115-5116 (1972)

Asymmetric reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli and Proteus species.

S P Hanlon et al.

Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)

The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic

Solvent free permanganate oxidations.

Shaabani A and Lee DG.

Tetrahedron Letters, 42(34), 5833-5836 (2001)

Global Trade Item Number

SKU	GTIN
294071-5G	04061837246883