294160
2-Methylaziridine
technical grade, 90%
Synonym(s):
Propyleneimine
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About This Item
Empirical Formula (Hill Notation):
C3H7N
CAS Number:
Molecular Weight:
57.09
EC Number:
200-878-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
102386
MDL number:
InChI key
OZDGMOYKSFPLSE-UHFFFAOYSA-N
InChI
1S/C3H7N/c1-3-2-4-3/h3-4H,2H2,1H3
SMILES string
CC1CN1
grade
technical grade
vapor pressure
140 mmHg ( 25 °C)
assay
90%
contains
sodium hydroxides as stabilizer
refractive index
n20/D 1.4125 (lit.)
bp
66-67 °C (lit.)
density
0.808 g/mL at 25 °C (lit.)
storage temp.
2-8°C
General description
2-Methylaziridine forms adduct with [60]fullerene, which on copolymerization with Novolac, Epon and Bisphenol A yields three dimensional polymers containing [60]fullerene with low coefficients of friction and good wear properties.
Application
2-Methylaziridine has been used in the synthesis of:
- new metallacycles and carbine complexes
- polyurethanes (thermoresponsive polymer) via copolymerization with supercritical CO2
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
14.0 °F
flash_point_c
-10 °C
Regulatory Information
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P N Floriano et al.
Journal of the American Chemical Society, 123(43), 10545-10553 (2001-10-25)
A family of diaminobutane core, poly(propylene imine) dendrimers coordinated to Cu(II), DAB-Am(n)-Cu(II)x (n = 4, 8, 16, 32, 64, x = n/2), was studied by means of extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) spectroscopies.
Theresa Chang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(28), 7883-7889 (2007-07-07)
The multiple monovalent binding of adamantyl-urea poly(propyleneimine) dendrimers with carboxylic acid-urea guests was investigated using molecular dynamics simulations and X-ray crystallography to better understand the structure and behavior of the dynamic multivalent complex in solution. The results from the two
E Murugan et al.
Journal of colloid and interface science, 357(2), 354-365 (2011-03-08)
Two multiwalled carbon nanotube hybrids have been prepared: (a) multiwalled carbon nanotubes (MWCNTs) functionalized with amphiphilic poly(propyleneimine) dendrimer (APPI), viz. MWCNTs-APPI, and (b) silver nanoparticles (AgNPs)-deposited multiwalled carbon nanotubes functionalized with an amphiphilic poly(propyleneimine) dendrimer (MWCNTs-APPI-AgNPs). The degree of covalent
E Holmes et al.
Comparative biochemistry and physiology. Part C, Pharmacology, toxicology & endocrinology, 116(2), 125-134 (1997-02-01)
The renal papillary toxin, propyleneimine (PI), was administered at 20 or 30 microliters/kg i.p. to male Sprague Dawley (SD) rats (n = 5), Fischer 344 (F344) rats (n = 4), and to multimammate desert mice (Mastomys natalensis, n = 4).
Kefilwe Vanessa Mokwebo et al.
Sensors (Basel, Switzerland), 18(10) (2018-10-12)
We report the preparation of poly (propylene imine) dendrimer (PPI) and CdTe/CdSe/ZnSe quantum dots (QDs) as a suitable platform for the development of an enzyme-based electrochemical cholesterol biosensor with enhanced analytical performance. The mercaptopropionic acid (MPA)-capped CdTe/CdSe/ZnSe QDs was synthesized
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