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294632

Methyl dimethoxyacetate

Name: Methyl dimethoxyacetate
Brand: ALDRICH

97%

Synonym(s):

Glyoxylic acid methyl ester dimethyl acetal

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About This Item

Linear Formula:

(CH₃O)₂CHCOOCH₃

CAS Number:

89-91-8

Molecular Weight:

134.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24857724

EC Number:

201-950-0

Beilstein/REAXYS Number:

1757582

MDL number:

MFCD00008484

Assay:

97%

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Properties

Quality Level

200

assay

97%

refractive index

n20/D 1.405 (lit.)

bp

67 °C/18 mmHg (lit.)

density

1.096 g/mL at 25 °C (lit.)

functional group

acetal, ester, ether

storage temp.

2-8°C

SMILES string

COC(OC)C(=O)OC

InChI

1S/C5H10O4/c1-7-4(6)5(8-2)9-3/h5H,1-3H3

InChI key

NZTCVGHPDWAALP-UHFFFAOYSA-N

Description

Application

Methyl dimethoxyacetate has been used:

in Claisen acylation of active hydrogen compounds
in preparation of 3, 9-disubstituted 2,4,8,10-tetroxaspiro [5.5] undecane
as Lithium enolate precursor
as acylating reagent for cycloalkanone enolates and amino alcohols

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

152.6 °F - closed cup

flash_point_c

67 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Regulatory Information

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HMG-CoA reductase inhibitors: design, synthesis, and biological activity of tetrahydroindazole-substituted 3,5-dihydroxy-6-heptenoic acid sodium salts.

P J Connolly et al.

Journal of medicinal chemistry, 36(23), 3674-3685 (1993-11-12)

Compounds comprising a series of 7-[2-(4-fluorophenyl)-4,5,6,7-tetrahydro-2H-indazol-3-yl]-3,5- dihydroxy-6-heptenoic acid sodium salts (18) were synthesized and tested for their ability to inhibit HMG-CoA reductase in a partially purified enzyme preparation and cholesterol biosynthesis from acetate in cultured HEP-G2 cells. Changing the size

Synthetic Communications, 23, 1003-1003 (1993)

Tetrahedron, 46, 6799-6799 (1990)

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Global Trade Item Number

SKU	GTIN
294632-25G	04061826601334