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295086

Sigma-Aldrich

trans-2-Butene

≥99%

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Synonym(s):
β-trans-Butylene, (2E)-2-Butene, (E)-2-Butene, 2-trans-Butene, 2-trans-Butylene, E-Butene, trans-1,2-Dimethylethylene, trans-2-Butylene, trans-Butene
Linear Formula:
CH3CH=CHCH3
CAS Number:
Molecular Weight:
56.11
Beilstein:
1718756
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

vapor density

2 (vs air)

Quality Level

vapor pressure

2575 mmHg ( 37.7 °C)

Assay

≥99%

autoignition temp.

615 °F

expl. lim.

9.7 %

bp

1 °C (lit.)

mp

−105 °C (lit.)

SMILES string

CC=CC

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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Application

trans-2-Butene can be used as a monomer unit to produce high molecular weight polyolefins with well-defined microstructures by nickle-catalyzed polymerization reaction. It is also used as a reactant in the isomerization reaction to produce the corresponding isomer using acid-activated catalysts.

Packaging

Supplied in a Sure/Pac cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
ISOGRO is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Pictograms

FlameGas cylinder

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Gas 1 - Press. Gas Liquefied gas

Storage Class Code

2A - Gases

WGK

WGK 3

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品

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Isomerization of cis-2-butene and trans-2-butene catalyzed by acid-and ion-exchanged smectite-type clays
Moronta A, et al.
Applied Clay Science, 29(2), 117-123 (2005)
Ni (II)-catalyzed polymerization of trans-2-butene
Leatherman MD and Brookhart M
Macromolecules, 34(9), 2748-2750 (2001)
Qiang Fu et al.
The Journal of chemical physics, 131(15), 154703-154703 (2010-06-24)
Adsorption and dehydrogenation processes of trans-2-butene molecule on the Pd(110) surface have been studied by density functional theory calculations. Different adsorption configurations of the reactant, the dehydrogenated product, and the most favorable reaction pathway have been determined. The calculated energy
H Nover et al.
Zentralblatt fur Bakteriologie, Mikrobiologie und Hygiene. 1. Abt. Originale B, Hygiene, 181(1-2), 71-80 (1985-06-01)
The multipurpose strain E. coli K12 343/113 allows the simultaneous detection of different DNA alterations such as base-pair changes, frameshifts and deletions. The investigations show the detection of mutagenic potency in the mixture which is called photochemical smog, produced by
Robert R Arnts
Environmental science & technology, 42(20), 7663-7669 (2008-11-06)
The continuous addition of trans-2-butene to air containing ozone-reactive volatile and semivolatile organic compounds prior to sampling on Tenax-TA adsorbent was found to be an effective means of removing ozone and reducing analyte losses of ozone reactive biogenic volatile organic

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