295337
Trifluoromethane
≥98%
Synonym(s):
Fluoroform, HFC-23
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About This Item
Linear Formula:
CHF3
CAS Number:
Molecular Weight:
70.01
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22
vapor density
2.43 (vs air)
vapor pressure
635 psi ( 21 °C)
Assay
≥98%
bp
−84 °C (lit.)
mp
−160 °C (lit.)
SMILES string
FC(F)F
InChI
1S/CHF3/c2-1(3)4/h1H
InChI key
XPDWGBQVDMORPB-UHFFFAOYSA-N
Packaging
Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.
Compatible with the following:
Compatible with the following:
- Aldrich® lecture-bottle station systems
- Aldrich® lecture-bottle gas regulators
Other Notes
See Technical Information Bulletin AL-151 Gas Regulators: Selection, Installation, and Operation
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Press. Gas Liquefied gas
Storage Class Code
2A - Gases
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Mark A Honey et al.
The Journal of organic chemistry, 77(3), 1396-1405 (2012-01-24)
Ethyl 2-diazo-4,4,4-trifluoro-3-oxobutanoate is a highly versatile intermediate for the synthesis of a wide range of trifluoromethyl heterocycles. With the use of rhodium(II) or copper(II) catalyzed carbene X-H insertion reactions as key steps, a diverse set of trifluoromethyl-oxazoles, -thiazoles, -imidazoles, -1,2,4-triazines
Charles S Thomoson et al.
The Journal of organic chemistry, 78(17), 8904-8908 (2013-08-13)
Fluoroform, CHF3, a non-ozone-depleting, nontoxic, and inexpensive gas can be used as a difluorocarbene source in a process for the conversion of phenols and thiophenols to their difluoromethoxy and difluorothiomethoxy derivatives. The reactions are carried out at moderate temperatures and
Shun Noritake et al.
Organic & biomolecular chemistry, 7(17), 3599-3604 (2009-08-14)
Chiral nonracemic guanidines act as Brønsted bases to generate guanidinium enolates for the enantioselective electrophilic trifluoromethylation of beta-keto esters by means of S-(trifluoromethyl)dibenzothiophenium tetrafluoroborate (Umemoto reagent) with good enantioselectivity of 60-70% range. Despite the fact that the ees are still
Nicolas Susperregui et al.
The Journal of organic chemistry, 75(19), 6581-6587 (2010-08-31)
The mechanism of ring-opening of ε-caprolactone by methanol catalyzed by trifluoromethane and methane sulfonic acids has been studied computationally at the DFT level of theory. For both elementary steps, the sulfonic acid was predicted to behave as a bifunctional catalyst.
Naeem Iqbal et al.
The Journal of organic chemistry, 77(24), 11383-11387 (2012-11-22)
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF(3)I, Ru(Phen)(3)Cl(2), and DBU. This process works especially well for terminal alkenes to give alkenyl-CF(3) products with only E-stereochemistry. The mild reaction conditions enable the
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