297976
Tributylborane solution
1.0 M in diethyl ether
Synonym(s):
TBB, Tributylboron
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About This Item
Linear Formula:
[CH3(CH2)3]3B
CAS Number:
Molecular Weight:
182.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
InChI
1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
SMILES string
CCCCB(CCCC)CCCC
InChI key
CMHHITPYCHHOGT-UHFFFAOYSA-N
reaction suitability
reagent type: reductant
concentration
1.0 M in diethyl ether
density
0.719 g/mL at 25 °C
Application
Reactant for:
- Addition reactions for synthesis of phenyltrialkylborate salts
- Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
- Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
- Multicomponent C-alkylation reactions with aromatic aldimines
- One-pot alkylation-boration and electrophilic substitution
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
Regulatory Information
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