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298352

(1S)-(−)-2,10-Camphorsultam

Name: (1<I>S</I>)-(−)-2,10-Camphorsultam
Brand: ALDRICH

98%

Synonym(s):

(−)-10,2-Camphorsultam, (−)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0^1,5]decane 3,3-dioxide, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₇NO₂S

CAS Number:

94594-90-8

Molecular Weight:

215.31

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24857980

MDL number:

MFCD00066271

Beilstein/REAXYS Number:

83811

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Properties

Quality Segment

200

assay

98%

form

solid

optical activity

[α]19/D −32°, c = 5 in chloroform

mp

181-183 °C (lit.)

SMILES string

[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C

InChI

1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1

InChI key

DPJYJNYYDJOJNO-NQMVMOMDSA-N

Description

General description

(1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.

Application

(1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.

ppe

dust mask type N95 (US), Eyeshields, Gloves

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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