301957
10-Camphorsulfonyl chloride
98%
Synonym(s):
Camphor-10-sulfonic acid chloride
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About This Item
Empirical Formula (Hill Notation):
C10H15ClO3S
CAS Number:
Molecular Weight:
250.74
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3205975
Assay:
98%
Form:
powder
InChI
1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m0/s1
SMILES string
CC1(C)[C@H]2CC[C@]1(CS(Cl)(=O)=O)C(=O)C2
InChI key
BGABKEVTHIJBIW-XVKPBYJWSA-N
assay
98%
form
powder
mp
66-68 °C (lit.)
Application
10-Camphorsulfonyl chloride was used in preparation of 1,2-bis(hydroxycamphorsulfonamido)cyclohexenes and 10-mercaptoisoborneol.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Asymmetric synthesis of nearly optically pure atrolactic acid methyl ether.
Eliel EL and Frazee WJ.
The Journal of Organic Chemistry, 44(20), 3598-3599 (1979)
Highly enantioselective addition of dialkylzinc reagents to ketones promoted by titanium tetraisopropoxide.
Yus M, et al.
Tetrahedron Asymmetry, 13(21), 2291-2293 (2002)
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