302570
N,N-Diethylpropionamide
99%
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About This Item
Linear Formula:
C2H5CON(C2H5)2
CAS Number:
Molecular Weight:
129.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
Form:
liquid
InChI
1S/C7H15NO/c1-4-7(9)8(5-2)6-3/h4-6H2,1-3H3
SMILES string
CCN(CC)C(=O)CC
InChI key
YKOQQFDCCBKROY-UHFFFAOYSA-N
assay
99%
form
liquid
refractive index
n20/D 1.442 (lit.)
bp
77 °C/12 mmHg (lit.)
density
0.897 g/mL at 25 °C (lit.)
General description
Gas phase ion/molecule reaction between dialkoxyborinium cation and N,N-diethylpropionamide was studied.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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X Zheng et al.
Journal of the American Society for Mass Spectrometry, 12(8), 948-955 (2001-08-17)
We report gas phase ion/molecule reactions between dialkoxyborinium cations (RO-B+-OR) and small organic amides, such as N,N-dimethylformamide and N,N-diethylpropionamide. Besides direct addition at boron, the results show efficient SN2 methyl transfer from the borinium ion to the amide. Isotopic labeling
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