305081
4-Methoxy-2-quinolinecarboxylic acid
95%
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About This Item
Empirical Formula (Hill Notation):
C11H9NO3
CAS Number:
Molecular Weight:
203.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C11H9NO3/c1-15-10-6-9(11(13)14)12-8-5-3-2-4-7(8)10/h2-6H,1H3,(H,13,14)
SMILES string
COc1cc(nc2ccccc12)C(O)=O
InChI key
AVBKMSSLAIKOGM-UHFFFAOYSA-N
assay
95%
mp
197 °C (dec.) (lit.)
Gene Information
rat ... Grin2a(24409)
General description
The redox chemistry of the ligand 4-methoxy-2-quinolinecarboxylic acid, its monoanion and its complexes with manganese(II) and manganese(III) was studied.
Application
4-Methoxy-2-quinolinecarboxylic acid was used in preparation of novel oxorhenium(V) complexes incorporating quinoline and isoquinoline carboxylic acid derivatives and 2,3-diaminopyridinium 4-methoxyquinoline-2-carboxylate.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Manganese (II) and (III) complexes with 4-methoxy-2-quinolinecarboxylic acid: Mono-and binuclear in aprotic medium.
Bodini ME and Arancibia MV.
Polyhedron, 11(17), 2195-2202 (1992)
Kaliyaperumal Thanigaimani et al.
Acta crystallographica. Section E, Structure reports online, 68(Pt 12), o3444-o3445 (2013-03-12)
In the 4-meth-oxy-quinoline-2-carboxyl-ate anion of the title salt, C5H8N3(+)·C11H8NO3(-), the dihedral angle between the quinoline ring system and the carboxyl-ate group is 16.54 (15)°. In the crystal, the cations and anions are linked via N-H⋯O and N-H⋯N hydrogen bonds, forming a
Barbara Machura et al.
Dalton transactions (Cambridge, England : 2003), 42(24), 8827-8837 (2013-05-04)
Six novel oxorhenium(V) complexes incorporating quinoline and isoquinoline carboxylic acid derivatives were prepared in good yields. Relying on the experimental conditions, compounds with two chelate ligands [ReOCl(iqc)2]·MeOH (1), [ReO(OMe)(iqc)2] (2), [ReO(OMe)(mqc)2] (3) and [ReO(OMe)(8-qc)2] (4) and compounds incorporating one bidentate
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