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307696

Cobalt(II) phthalocyanine

Name: Cobalt(II) phthalocyanine
Brand: ALDRICH

β-form, Dye content 97 %

Synonym(s):

Cobaltous phthalocyaninate, PcCo, Phthalocyanine cobalt(II) salt

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About This Item

Empirical Formula (Hill Notation):

C₃₂H₁₆CoN₈

CAS Number:

3317-67-7

Molecular Weight:

571.46

UNSPSC Code:

12352103

NACRES:

NA.23

PubChem Substance ID:

24858616

EC Number:

222-012-7

Beilstein/REAXYS Number:

4121847

MDL number:

MFCD00010718

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Properties

Quality Level

200

form

powder

composition

Dye content, 97%

SMILES string

[Co]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Co/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

MPMSMUBQXQALQI-UHFFFAOYSA-N

Description

General description

Cobalt(II) phthalocyanine (CoPC )is a metallopthalocyanine.

Application

Self assembled molecules of CoPC were deposited on epitaxial graphene. CoPC may be used to develop carbon black based electrocatalysts. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalysed aerobic regenerations of aldehydes and ketones have been investigated. CoPC may also be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol.

pictograms

GHS08

signalword

Warning

hcodes

H351

pcodes

P201 - P308 + P313

Hazard Classifications

Carc. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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The use of copper and cobalt phthalocyanines as electrocatalysts for the oxygen reduction reaction in acid medium.

Reis RM, et al.

Electrochimica Acta, 139, 1-6 (2014)

Microfabricated glucose biosensor for culture well operation.

R M Pemberton et al.

Biosensors & bioelectronics, 42, 668-677 (2012-12-26)

A water-based carbon screen-printing ink formulation, containing the redox mediator cobalt phthalocyanine (CoPC) and the enzyme glucose oxidase (GOx), was investigated for its suitability to fabricate glucose microbiosensors in a 96-well microplate format: (1) the biosensor ink was dip-coated onto

Proton-coupled electron-transfer reduction of dioxygen catalyzed by a saddle-distorted cobalt phthalocyanine.

Tatsuhiko Honda et al.

Journal of the American Chemical Society, 134(9), 4196-4206 (2012-02-04)

Proton-coupled electron-transfer reduction of dioxygen (O(2)) to afford hydrogen peroxide (H(2)O(2)) was investigated by using ferrocene derivatives as reductants and saddle-distorted (α-octaphenylphthalocyaninato)cobalt(II) (Co(II)(Ph(8)Pc)) as a catalyst under acidic conditions. The selective two-electron reduction of O(2) by dimethylferrocene (Me(2)Fc) and decamethylferrocene

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Global Trade Item Number

SKU	GTIN
307696-1G	04061826673751
307696-50G	04061826673768
307696-10G	04061826673744