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308064

2-(Trimethylsiloxy)furan

Name: 2-(Trimethylsiloxy)furan
Brand: ALDRICH

97%

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About This Item

Empirical Formula (Hill Notation):

C₇H₁₂O₂Si

CAS Number:

61550-02-5

Molecular Weight:

156.25

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24858645

MDL number:

MFCD00011729

Beilstein/REAXYS Number:

1423066

Assay:

97%

Form:

liquid

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Properties

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.436 (lit.)

bp

34-35 °C/9 mmHg (lit.)

density

0.929 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

C[Si](C)(C)Oc1ccco1

InChI

1S/C7H12O2Si/c1-10(2,3)9-7-5-4-6-8-7/h4-6H,1-3H3

InChI key

ILBCDLOQMRDXLN-UHFFFAOYSA-N

Description

Disclaimer

Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

64.4 °F - closed cup

flash_point_c

18 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Simple diastereoselectivity of the BF3.OEt2-catalyzed vinylogous Mukaiyama aldol reaction of 2-(trimethylsiloxy)furans with aldehydes.

Carlos Silva López et al.

The Journal of organic chemistry, 70(9), 3654-3659 (2005-04-23)

[reaction: see text] A comprehensive scan of the transition state space for the reaction of 2-(trimethylsiloxy)furan and methacrolein (24 combinations) offered a satisfactory explanation of the high like diastereoselectivity obtained experimentally in the Mukaiyama vinylogous aldol reaction of these and

Global Trade Item Number

SKU	GTIN
308064-5G	04061826674291
308064-1G	04061837714245