309281
Iron(III) perchlorate hydrate
crystalline
Synonym(s):
Perchloric acid iron(III) salt hydrate
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About This Item
Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
Molecular Weight:
354.20 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
236-908-0
MDL number:
Form:
crystalline
form
crystalline
Quality Level
reaction suitability
reagent type: oxidant
impurities
<0.10% chloride
color
yellow
SMILES string
[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI
1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
InChI key
PFPIMAZLJXJVAN-UHFFFAOYSA-K
Application
Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.
It can be used as a catalyst for synthesis of:
It can be used as a catalyst for synthesis of:
- Fullerene-fused lactones
- α-Carbonyl furans via one-pot cyclization
- Fullerodioxolanes via heterocyclization
- Fulleroxazolidines
- Dialylated indoles via double alkylation
- Aryl esters via oxidative esterification
Catalyst for synthesis of:
Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution
Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
- Fullerene-fused lactones
- α-Carbonyl furans via one-pot cyclization
- Fullerodioxolanes via heterocyclization
- Dialylated indoles via double alkylation
- Aryl esters via oxidative esterification
Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution
Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.
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signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Diverse redox chemistry of photo/ferrioxalate system.
Wang Z, et al.
Royal Society of Chemistry Advances, 4(84), 44654-44658 (2014)
Iron salt-catalyzed cascade type one-pot double alkylation of indole with vinyl ketones.
Kobayashi JK, et al.
Tetrahedron, 66(22), 3917-3922 (2010)
Ferric Perchlorate Promoted Reaction of [60] Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines.
Liu TX, et al.
The Journal of Organic Chemistry, 80(24), 11986-11992 (2015)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 309281-100G | 04061826675564 |