316954
Ammonium perrhenate
≥99%
Synonym(s):
Metaperrhenic acid ammonium salt, Rhenium standard solution
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About This Item
Linear Formula:
NH4ReO4
CAS Number:
Molecular Weight:
268.24
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
≥99%
Form:
powder or crystals
Assay
≥99%
form
powder or crystals
reaction suitability
reagent type: catalyst
density
3.97 g/mL at 25 °C (lit.)
SMILES string
N.O[Re](=O)(=O)=O
InChI
1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1
InChI key
XPSXHXWHJAIQJR-UHFFFAOYSA-M
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General description
Ammonium perrhenate is a white crystalline solid soluble in ethanol and water. It is a weak oxidizer and widely used as a Re precursor in nanomaterial synthesis and Re-based catalyst preparation.
Application
Ammonium perrhenate used:
- As a rhenium source to prepare Re nanoparticles for catalytic decomposition of ammonium perchlorate.
- To synthesize ReS2 through a direct sulfidation reaction, for the fabrication of field effect transistors (FETs), digital logic devices, humidity sensors, and rechargeable supercapacitors.
- As a precursor to prepare the heterogeneous catalysts for organic transformations.
- An excellent precursor for the fabrication of ReOx/TiO2 recyclable solidcatalyst for deoxydehydration. For at least six runs in a row, the catalyst demonstrated catalyticactivity, selectivity, and stability without deactivation.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Perez-Lourido, P. et al.
Inorganic Chemistry, 38, 1511-1511 (1999)
Xuezeng Tian et al.
Nature materials, 19(8), 867-873 (2020-03-11)
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