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323438

Tetraamminepalladium(II) chloride monohydrate

≥99.99% trace metals basis, powder or crystals

Synonym(s):

Tetraamminepalladium(2+) dichloride monohydrate

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About This Item

Linear Formula:
Pd(NH3)4Cl2·H2O
CAS Number:
13933-31-8
Molecular Weight:
263.46
NACRES:
NA.22
PubChem Substance ID:
24859365
UNSPSC Code:
12161600
EC Number:
237-489-7
MDL number:
MFCD00151033
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Product Name

Tetraamminepalladium(II) chloride monohydrate, ≥99.99% trace metals basis

Quality Level

100

assay

≥99.99% trace metals basis

form

powder or crystals

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

120 °C (dec.) (lit.)

density

1.91 g/mL at 25 °C (lit.)

SMILES string

N.N.N.N.O.Cl[Pd]Cl

InChI

1S/2ClH.4H3N.H2O.Pd/h2*1H;4*1H3;1H2;/q;;;;;;;+2/p-2

InChI key

WVCXSPJPERKPJS-UHFFFAOYSA-L

General description

Tetraamminepalladium (II) chloride monohydrate is used as a precursor to synthesize palladium nanoparticles and Pd (II) complexes.

Application

Tetraamminepalladium(II) chloride monohydrate can be used as a:
  • Precursor for the synthesis of Pd nanoparticles on carbon supports, which is an efficient catalyst for the selective reduction of nitrite to nitrogen.
  • Starting material for the synthesis of a Pd (II) complex which can be immobilized on different substrates to create catalysts with high catalytic activity.

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pictograms

Exclamation mark
GHS07

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB1959
MKCZ4252
MKCX7233
MKCX1326
MKCW1657

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Selective reduction of nitrite to nitrogen with carbon-supported Pd--AOT nanoparticles
Perez-Coronado AM, et al.
Journal of Industrial and Engineering Chemistry, 56(41), 11745-11754 (2017)
Immobilization of a Pd (II) complex on hydrophilic graphite oxide and its catalytic investigation in the Heck coupling reaction
Mastalir A, et al.
Applied Organometallic Chemistry, 34(4), e5565-e5565 (2020)

Global Trade Item Number

SKUGTIN
323438-1G04061826708644
323438-5G04061826708651