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Merck
CN

325066

(R)-(−)-3-Bromo-2-methyl-1-propanol

97%

Synonym(s):

(R)-3-Bromo-2-methylpropan-1-ol, (R)-3-Hydroxy-2-methylpropyl bromide, 3-Bromo-2-(R)-methyl-1-propanol

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About This Item

Linear Formula:
BrCH2CH(CH3)CH2OH
CAS Number:
93381-28-3
Molecular Weight:
153.02
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
24859485
MDL number:
MFCD00013302
Beilstein/REAXYS Number:
3600269

Key Documents

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Product Name

(R)-(−)-3-Bromo-2-methyl-1-propanol, 97%

InChI

1S/C4H9BrO/c1-4(2-5)3-6/h4,6H,2-3H2,1H3/t4-/m0/s1

SMILES string

C[C@H](CO)CBr

InChI key

KIBOHRIGZMLNNS-BYPYZUCNSA-N

assay

97%

form

liquid

optical activity

[α]25/D −6.6°, c = 2 in chloroform

refractive index

n20/D 1.484 (lit.)

bp

73-74 °C/9 mmHg (lit.)

density

1.461 g/mL at 20 °C (lit.)

functional group

bromo
hydroxyl

Quality Level

100

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Application

(R)-(−)-3-Bromo-2-methyl-1-propanol is used as a starting material in the total syntheses of epothilone C and bistramide A. It can also be used as a structural modifier in the homochiral porous molecular networks.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR5459
SHBD7795V
SHBC3181V
SHBC0589V
35596DMV

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Multi?step application of immobilized reagents and scavengers: a total synthesis of epothilone C.
Storer R I, et al.
Chemistry?A European Journal , 10(10), 2529-2547 (2004)
Enantioselective total synthesis of bistramide A.
Crimmins M T and DeBaillie A C
Journal of the American Chemical Society, 128(15), 4936-4937 (2006)
Control and induction of surface-confined homochiral porous molecular networks.
Tahara K, et al.
Nature Chemistry, 3(9), 714-719 (2011)

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