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Merck
CN

328642

Sigma-Aldrich

Borohydride, polymer-supported

support is Amberlyst® IRA-400, Macroporous, 20-50 mesh, extent of labeling: ~2.5 mmol/g loading

Synonym(s):

Borohydride on Amberlite IRA-400, (Polystyrylmethyl)trimethylammonium borohydride

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About This Item

MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.22
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form

beads

reaction suitability

reaction type: solution phase peptide synthesis
reactivity: carbonyl reactive

extent of labeling

~2.5 mmol/g loading

particle size

20-50 mesh

SMILES string

[H][B-]([H])([H])[H].C=Cc1ccccc1.C=Cc2ccc(C=C)cc2.C[N+](C)(C)Cc3ccccc3

InChI

1S/C4H12N.BH4/c1-5(2,3)4;/h1-4H3;1H4/q+1;-1

InChI key

LSSMEJCYZMCNIN-UHFFFAOYSA-N

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Application

Reagent for selective reduction of α,β-unsaturated aldehydes and ketones to allylic alcohols.

Legal Information

Amberlite is a trademark of DuPont de Nemours, Inc.
Amberlyst is a registered trademark of The Dow Chemical Company or an affiliated company of Dow

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Gibson, H.W.;Bailey, J.
Journal of the Chemical Society, 815-815 (1997)
Sande, A.R.
Tetrahedron Letters, 25, 3501-3501 (1984)
Yoon, N.M.
Tetrahedron Letters, 24, 5367-5367 (1983)
A. Nag et al.
Synthetic Communications, 17, 1007-1007 (1987)

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