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Merck
CN

328987

Phenyl chlorodithioformate

95%

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About This Item

Linear Formula:
ClCS2C6H5
CAS Number:
Molecular Weight:
188.70
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
liquid
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InChI

1S/C7H5ClS2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H

SMILES string

ClC(=S)Sc1ccccc1

InChI key

XEXIHCWFFNGQDE-UHFFFAOYSA-N

assay

95%

form

liquid

refractive index

n20/D 1.6688 (lit.)

bp

135 °C/15 mmHg (lit.)

density

1.331 g/mL at 25 °C (lit.)

functional group

chloro, thioether

storage temp.

2-8°C

Quality Level

General description

Kinetics and mechanism of solvolysis reaction of phenyl chlorodithioformate was reported.

Application

Phenyl chlorodithioformate was used in synthesis of phenyl arylsulfonyl-alkyl-dithiocarbamates. It was also used in synthesis of S-phenyl O-(4-nitrophenyl)dithiocarbonate.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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The nucleofuge in the pyridinolysis of O-(4-nitrophenyl) S-aryl thio and dithiocarbonates.
Castro EA, et al.
Journal of Physical Organic Chemistry, 25(11), 994-994 (2012)
Kinetics and mechanism of the reactions of aryl chlorodithioformates with pyridines and secondary alicyclic amines.
Castro EA, et al.
Journal of Physical Organic Chemistry, 22(11), 1030-1037 (2009)
Synthesis of Phenyl Arylsulfonyl-alkyl-dithiocarbamates and Their Hydrolytic Reactivity in Hydroxide and Hydroperoxide Media.
Norberto F, et al.
European Journal of Organic Chemistry, 2005(21), 4710-4714 (2005)

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